光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
*A48shfO qY%|Uo 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
s%R,]q k*2khh- 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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p9G+la~;VM a.UYBRP/l 目录
-a|b.p 1. Introduction and Basic Principles
F(/<ADx 1.1 Historical Development
<tZtt9j_ 1.2 The Electron Mean Free Path
I&i6-xp 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
$FT6c@&y 1.4 Experimental Aspects
Jo[&y, 1.5 Very High Resolution
R*cef 1.6 The Theory of Photoemission
!!ZGNZ_ 1.6.1 Core-Level Photoemission
vCt][WX( 1.6.2 Valence-State Photoemission
ex~"M&^ 1.6.3 Three-Step and One-Step Considerations
W!" $g 1.7 Deviations from the Simple Theory of Photoemission
#"r_ 3 References
D0bpD qB@N|Bb 2. Core Levels and Final States
@b 17jmq{ 2.1 Core-Level Binding Energies in Atoms and Molecules
y[Dgyt 2.1.1 The Equivalent-Core Approximation
F
]D^e{y 2.1.2 Chemical Shifts
wpN [0^M-0 2.2 Core-Level Binding Energies in Solids
jT0iJ?d,! 2.2.1 The Born-Haber Cycle in Insulators
\rh+\9( 2.2.2 Theory of Binding Energies
}+`,AC`RM 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
lz>.mXdx 2.3 Core Polarization
R(_WTs9x4 2.4 Final-State Multiplets in Rare-Earth Valence Bands
^FNju/b 2.5 Vibrational Side Bands
YVF@v-v-, 2.6 Core Levels of Adsorbed Molecules
=v?V 2.7 Quantitative Chemical Analysis from Core-Level Intensities
u&={hJ&7 References
4Hyp]07 3:$@DZT$ 3. Charge-Excitation Final States: Satellites
;mD!8<~z. 3.1 Copper Dihalides; 3d Transition Metal Compounds
nzAySMD_ 3.1.1 Characterization of a Satellite
RFe>#o 3.1.2 Analysis of Charge-Transfer Satellites
t6e6v=.Pg 3.1.3 Non-local Screening
IAb.Z+ig 3.2 The 6-eV Satellite in Nickel
&uaSp,L 3.2.1 Resonance Photoemission
leSBR,C 3.2.2 Satellites in Other Metals
,f?B((l 3.3 The Gunnarsson-Sch6nhammer Theory
KDP&I J 3.4 Photoemission Signals and Narrow Bands in Metals
beYGP References
D=D.s)ns* N1y,~Z 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
1=>b\"P#E 4.1 Theory
I%[Tosud< 4.1.1 General
07(LLhk@d 4.1.2 Core-Line Shape
2C"i2/NH' 4.1.3 Intrinsic Plasmons
'>bn94$ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
iSX:H; 4.1.5 The Total Photoelectron Spectrum
fK(:vwh 4.2 Experimental Results
.;bU["fn) 4.2.1 The Core Line Without Plasmons
!p36OEx 4.2.2 Core-Level Spectra Including Plasmoas
eln$,zK/b 4.2.3 Valence-Band Spectra of the Simple Metals
L1 k 4.2.4 Simple Metals: A General Comment
3-;<G 4.3 The Background Correction
x>K,{{B)X References
qgWsf-di= GX.a!XQ@! 5. Valence Orbitals in Simple Molecules and Insulating Solids
p@DVy2,EY 5.1 UPS Spectra of Monatomic Gases
a|dgK+[ 5.2 Photoelectron Spectra of Diatomic Molecules
~S
:8M<aB 5.3 Binding Energy of the H2 Molecule
u
XZ ;K. 5.4 Hydrides Isoelectronic with Noble Gases
kyYU 1gfh Neon (Ne)
]w-W Hydrogen Fluoride (HF)
wB[
JFy"E Water (H2O)
1v|0&{lB Ammonia (NH3)
@YS,)U)4S Methane (CH4)
X,8Zn06M 5.5 Spectra of the Alkali HMides
_S &6XNV 5.6 Transition Metal Dihalides
H-m).^ 5.7 Hydrocarbons
1]8Hpd 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
51AA,"2[_ 5.7.2 Linear Polymers
%vG;'_gMB 5.8 Insulating Solids with Valence d Electrons
YWANBM(v+ 5.8.1 The NiO Problem
X2np.9hie 5.8.2 Mort Insulation
}LWrtmc 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
Vd)
%qw 5.8.4Band Structures of Transition Metal Compounds
"x:-#2+h 5.9 High—Temperature Superconductors
@@!]Raj= 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
h^{aG ]) 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
o/RGz PR 5.9.3 The Superconducting Gap
{FC<vx{42 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
*`bES V
: 5.9.5 Core—Level Shifts
+).=}.k 5.10 The Fermi Liquid and the Luttinger Liquid
0@&;JMh6< 5.11 Adsorbed Molecules
u
VUrg;> 5.11.1 Outline
6k7x7z 5.11.2 CO on Metal Surfaces
0*uJS`se6Z References
zJ8 jJFL+Y 4;IZ}9|G 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
bg|=)sw4 6.1 Theory of Photoemission:A Summary of the Three-Step Model
jfa<32`0E 6.2 Discussion of the Photocurrent
'
#t1e] 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
$nf
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m Le
70U 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
gp{Z]{io 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
%we! J%'Y] 6.3.1 Band Structure Regime
eQ#"-i 6.3.2 XPS Regime
PXDJ[Oj7(0 6.3.3 Surface Emission
3/su 1M[ 6.3.4 One-Step Calculations
ar`}+2Qh0 6.4 Thermal Effects
eTtiAF=bW 6.5 Dipole Selection Rules for Direct Optical Transitions
(Y?}'? References
7'{Y7]+z+ C*Y0GfW= 7.Band Structtire and Angular-Resolved Photoelectron Spectra
s*>B"#En 7.1 Free-Electron Final—State Model
$A: ?o?"7} 7.2 Methods Employing Calculated Band Structures
n4AQ 7.3 Methods for the Absolute Determination of the Crystal Momentum
DCCij N 7.3.1 Triangulation or Energy Coincidence Method
c
8|&Q 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
V#DNcF~v]f 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
Q(hAV 7.3.4 The Surface Emission Method and Electron Damping
t$uj( y> 7.3.5 The Very-Low-Energy Electron Diffraction Method
H]0(GLvH 7.3.6 The Fermi Surface Method
x Sv@K5"8! 7.3.7 Intensities and Their Use in Band-Structure Determinations
%BkPkQA 7.3.8 Summary
hl+
T 7.4 Experimental Band Structures
&!8u4*K5j 7.4.1 One- and Two-Dimensional Systems
{1vlz>82 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
pA5X<)~
7..4.3UPS Band Structures and XPS Density of States
yjChnp
Cc 7.5 A Comment
j&,%v+x References
GYri\ <[ )-LSn 8.Surface States, Surface Effects
wpJfP_H 8.1 Theoretical Considerations
*3y:Wv T> 8.2 Experimental Results on Surface States
I}/-zyx>= 8.3 Quantum-Well States
pW2-RHGJY 8.4 Surface Core-Level Shifts
@0%^\Qf2 References
kc"SUiy/ Ktf lbI! 9.Inverse Photoelectron Spectroscopy
G^w:c] 9.1 Surface States
F:2V; 9.2 Bulk Band Structures
=Wl}Pgo! 9.3 Adsorbed Molecules
|uln<nM9 References
>Co5_sCe Y/n],(t) 10. Spin-Polarized Photoelectron Spectroscopy
(wEaw|Zx 10.1 General Description
=a./HCF 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
j1P#({z[ 10.3 Magnetic Dichroism
:]IYw!_-p References
pGSS
;kF+V* 11. Photoelectron Diffraction
l0{R`G, 11.1 Examples
K(p6P3Z 11.2 Substrate Photoelectron Diffraction
4VfZw\^ 11.3 Adsorbate Photoelectron Diffraction
| <l=i( 11.4 Fermi Surface Scans
lhx]r}@'MC References
3R$*G8v AU^5N3%j Appendix
Ba]^0Y
u A.1 Table of Binding Energies
dht*1i3v A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
6
VuMx7W1 A.3 Compilation of Work Functions
c{K[bppJ* References
r4Jc9Tvd Index