光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
)[0T16 JD@J[YY5R 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
\drqG&wl eP*lI<NQ1 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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?\C"YG69T s!n<}C 目录
@-UL`+ 1. Introduction and Basic Principles
eF[63zx5* 1.1 Historical Development
5>BK%` 1.2 The Electron Mean Free Path
GpZc5c 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
?5_7;Ha 1.4 Experimental Aspects
T,|
1g6 1.5 Very High Resolution
i4^o59}8 1.6 The Theory of Photoemission
(Qa/EkE^*w 1.6.1 Core-Level Photoemission
ylt`*|$ 1.6.2 Valence-State Photoemission
(`y*V;o4 1.6.3 Three-Step and One-Step Considerations
N<QXmgqx 1.7 Deviations from the Simple Theory of Photoemission
Yjx|9_|Xn References
B}PIRk@a1 ?LvCR_D: 2. Core Levels and Final States
%Gt.m 2.1 Core-Level Binding Energies in Atoms and Molecules
z5)s/;Sc 2.1.1 The Equivalent-Core Approximation
<.Nx[!'~&d 2.1.2 Chemical Shifts
(SKVuR%Jj 2.2 Core-Level Binding Energies in Solids
os/vtyP:a 2.2.1 The Born-Haber Cycle in Insulators
0GJn_@hr 2.2.2 Theory of Binding Energies
jBegh9KHq 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
R
{-5Etv 2.3 Core Polarization
],P;WPU 2.4 Final-State Multiplets in Rare-Earth Valence Bands
,3@#F/c3i~ 2.5 Vibrational Side Bands
7Hm3;P. 2.6 Core Levels of Adsorbed Molecules
oWYmj=D~2z 2.7 Quantitative Chemical Analysis from Core-Level Intensities
y@\V+ References
Q+YRf3$ jQ:OKh<Y 3. Charge-Excitation Final States: Satellites
r$2P;Cxj 3.1 Copper Dihalides; 3d Transition Metal Compounds
Fd0%lnui 3.1.1 Characterization of a Satellite
Dk?\)lD` 3.1.2 Analysis of Charge-Transfer Satellites
33!oS&L 3.1.3 Non-local Screening
lbpq_= 3.2 The 6-eV Satellite in Nickel
} \ZaE~ 3.2.1 Resonance Photoemission
F&&$Qn_+ 3.2.2 Satellites in Other Metals
lV%N 3.3 The Gunnarsson-Sch6nhammer Theory
,_Z+8 3.4 Photoemission Signals and Narrow Bands in Metals
;VWAf;U;B References
}Hn/I,/ fMOU$0]$< 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
|+T1XYG5 4.1 Theory
0{=`on; 4.1.1 General
j$+nKc$ 4.1.2 Core-Line Shape
y\a1iy 4.1.3 Intrinsic Plasmons
xD6@Qk 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
b#X^=n2 4.1.5 The Total Photoelectron Spectrum
o
LvZ 4.2 Experimental Results
B>2tZZko 4.2.1 The Core Line Without Plasmons
Z?\2F% 4.2.2 Core-Level Spectra Including Plasmoas
'#k0a,<N 4.2.3 Valence-Band Spectra of the Simple Metals
ONe# rKJ_ 4.2.4 Simple Metals: A General Comment
}`@728E
4.3 The Background Correction
iRrl^\qn References
P'`r JfR%L q~ 5. Valence Orbitals in Simple Molecules and Insulating Solids
ariLG [:X 5.1 UPS Spectra of Monatomic Gases
2RX!V@z.G 5.2 Photoelectron Spectra of Diatomic Molecules
bua+I;b 5.3 Binding Energy of the H2 Molecule
zzyHoZJP 5.4 Hydrides Isoelectronic with Noble Gases
gXjV?"^kUl Neon (Ne)
!_"fP:T> Hydrogen Fluoride (HF)
B&@?*^. Water (H2O)
nVi[ Ammonia (NH3)
[Nk3|u`h Methane (CH4)
~m$Y$,uH 5.5 Spectra of the Alkali HMides
;1a~pF S 5.6 Transition Metal Dihalides
-YCOP0 5.7 Hydrocarbons
{HCzp,Y 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
;A*`e$ 5.7.2 Linear Polymers
49vcoHlf 5.8 Insulating Solids with Valence d Electrons
tQjLOv+?= 5.8.1 The NiO Problem
ZSG9t2qlv 5.8.2 Mort Insulation
*FM Mjz 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
0:T|S>FsAm 5.8.4Band Structures of Transition Metal Compounds
Y 1t\iU 5.9 High—Temperature Superconductors
o}$EG 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
}yz (xH 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
pim!.=vN/U 5.9.3 The Superconducting Gap
2n|K5FR() 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
i{`;R 5.9.5 Core—Level Shifts
2'W<h)m)z 5.10 The Fermi Liquid and the Luttinger Liquid
xLC3>>P 5.11 Adsorbed Molecules
7eiV{ tYF 5.11.1 Outline
7D;cw\ | 5.11.2 CO on Metal Surfaces
Gy6l<:; References
WUh$^5W lb3]$Da
6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
FGoy8+nB1M 6.1 Theory of Photoemission:A Summary of the Three-Step Model
XR;eY:89 6.2 Discussion of the Photocurrent
+>r/ 0b 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
+w+}b^4 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
z&fwE$Nm 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
=,UWX3`f 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
,d {"m)r< 6.3.1 Band Structure Regime
[_Qa9e 6.3.2 XPS Regime
vuoQz\ 6.3.3 Surface Emission
J{k79v 6.3.4 One-Step Calculations
;oy-#p>N% 6.4 Thermal Effects
L{8xlx` 6.5 Dipole Selection Rules for Direct Optical Transitions
28UU60 References
RH&~+5 '7iSp= 7.Band Structtire and Angular-Resolved Photoelectron Spectra
G{6;>8h 7.1 Free-Electron Final—State Model
<psZQdH 7.2 Methods Employing Calculated Band Structures
Ro9tZ'N!S
7.3 Methods for the Absolute Determination of the Crystal Momentum
~V\D|W9 7.3.1 Triangulation or Energy Coincidence Method
PEW=@xj2y 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
~,i-8jl, 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
#6CC3TJ'k 7.3.4 The Surface Emission Method and Electron Damping
<y?r!l=Am 7.3.5 The Very-Low-Energy Electron Diffraction Method
Kq;8=xP[ 7.3.6 The Fermi Surface Method
ybY]e; v*O 7.3.7 Intensities and Their Use in Band-Structure Determinations
!;KCU^9 7.3.8 Summary
4#:W.]U8 7.4 Experimental Band Structures
'LO^< 7.4.1 One- and Two-Dimensional Systems
j4cwI90= 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
Ndi9FD3im 7..4.3UPS Band Structures and XPS Density of States
z}*9uZ 7.5 A Comment
oz}+T(@O References
!X;1 } 7G/1VeVjB 8.Surface States, Surface Effects
/assq+H 8.1 Theoretical Considerations
f)^_|8 8.2 Experimental Results on Surface States
\uaJ@{Vug 8.3 Quantum-Well States
% a@>_ 8.4 Surface Core-Level Shifts
V 7Ek-2M References
1$p2}Bf{n ^h"`}[+ 9.Inverse Photoelectron Spectroscopy
*%S"eWb 9.1 Surface States
pQtJc*[! 9.2 Bulk Band Structures
#0y)U;dA+w 9.3 Adsorbed Molecules
}MH0L#Tu References
@CZT /Sc l#4bW 10. Spin-Polarized Photoelectron Spectroscopy
g.zEn/SM 10.1 General Description
{l/-LZ. 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
A^y|J`k| 10.3 Magnetic Dichroism
RM!<8fXYD References
9mmCp&~Z 8q,6}mV
11. Photoelectron Diffraction
T<55a6NoK 11.1 Examples
Cc%LztP> 11.2 Substrate Photoelectron Diffraction
s#)5h0t#du 11.3 Adsorbate Photoelectron Diffraction
ck.w
5|$ 11.4 Fermi Surface Scans
L;'"A#Pa References
WYEKf9} #]ypHVE Appendix
cM$P`{QrM A.1 Table of Binding Energies
to=y#$_ A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
YW60q0: A.3 Compilation of Work Functions
g!+|I References
"3)4vuX@;c Index