光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
2<'gX>TW 9#agI|d~ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
1HZexV Z86[sQBg 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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HgMDw/D( d,>l;l 目录
\GkcK$Y 1. Introduction and Basic Principles
EUNG&U 1.1 Historical Development
d
EXw=u 1.2 The Electron Mean Free Path
W}e5 4-lu 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
</}[x2w?] 1.4 Experimental Aspects
57#:GN$EL 1.5 Very High Resolution
,5/gNg 1.6 The Theory of Photoemission
i7p3GBXh[ 1.6.1 Core-Level Photoemission
z6Hl+nq B 1.6.2 Valence-State Photoemission
;CC[> 1.6.3 Three-Step and One-Step Considerations
F
|GWYw'% 1.7 Deviations from the Simple Theory of Photoemission
t9=rr>8) References
#(A>yW702 4f1*?HX& 2. Core Levels and Final States
aJfW75C 2.1 Core-Level Binding Energies in Atoms and Molecules
6tJM*{$$H 2.1.1 The Equivalent-Core Approximation
~vt8|OOo0 2.1.2 Chemical Shifts
C{,nDa?| 2.2 Core-Level Binding Energies in Solids
UR\*KR;yM 2.2.1 The Born-Haber Cycle in Insulators
4f>Vg$4 2.2.2 Theory of Binding Energies
2
o.Mh/D0 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
c1Hv^*Y 2.3 Core Polarization
AvwX 2?tc 2.4 Final-State Multiplets in Rare-Earth Valence Bands
P--#5W;^oB 2.5 Vibrational Side Bands
ei"FN3 Rm 2.6 Core Levels of Adsorbed Molecules
1,/oS&?E 2.7 Quantitative Chemical Analysis from Core-Level Intensities
p'R}z|d) References
^o{O5&i] Axcm~!uf 3. Charge-Excitation Final States: Satellites
:xA'X+d/' 3.1 Copper Dihalides; 3d Transition Metal Compounds
>Qi2;t~G 3.1.1 Characterization of a Satellite
'Kq%tM26! 3.1.2 Analysis of Charge-Transfer Satellites
{:"bX~<^ 3.1.3 Non-local Screening
LsmC/+7r$1 3.2 The 6-eV Satellite in Nickel
YlYTH_L>E 3.2.1 Resonance Photoemission
phNv^R+ 3.2.2 Satellites in Other Metals
v3[
2!UXq 3.3 The Gunnarsson-Sch6nhammer Theory
1ptP ey 3.4 Photoemission Signals and Narrow Bands in Metals
EBn7waBS References
S4\T ( [#.QDe 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
LsLsSV 4.1 Theory
P!-9cd1C, 4.1.1 General
r..Rh9v/=E 4.1.2 Core-Line Shape
VJPt/Dy{ 4.1.3 Intrinsic Plasmons
3cs'Oz<w 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
+DU}f;O8v 4.1.5 The Total Photoelectron Spectrum
jbG #__#_ 4.2 Experimental Results
toP7b 4.2.1 The Core Line Without Plasmons
Z*oGVr
g 4.2.2 Core-Level Spectra Including Plasmoas
~UL;O\-b0 4.2.3 Valence-Band Spectra of the Simple Metals
,H|V\\ 4.2.4 Simple Metals: A General Comment
H_jMl$f)j 4.3 The Background Correction
1c\$ziB References
khyVuWN
-ERDW Y 5. Valence Orbitals in Simple Molecules and Insulating Solids
tW 9vo-{+ 5.1 UPS Spectra of Monatomic Gases
jirxzj 5.2 Photoelectron Spectra of Diatomic Molecules
:V >Z|?[*H 5.3 Binding Energy of the H2 Molecule
OpiN,>; 5.4 Hydrides Isoelectronic with Noble Gases
mH;\z;lyK Neon (Ne)
+H+OYQ>^ Hydrogen Fluoride (HF)
i5rAb<q` Water (H2O)
zEa3a Ammonia (NH3)
k/*r2 C Methane (CH4)
o8Tt|Lxb$8 5.5 Spectra of the Alkali HMides
RU@`+6j+ 5.6 Transition Metal Dihalides
oo<,hOv 5.7 Hydrocarbons
SkS
vu} 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
yQ h":"$k 5.7.2 Linear Polymers
k|&@xEbS
5.8 Insulating Solids with Valence d Electrons
0*+i~g,Kl@ 5.8.1 The NiO Problem
[X;yJ $ 5.8.2 Mort Insulation
_O)~<Sk-*z 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
dMYDB 5.8.4Band Structures of Transition Metal Compounds
mhVSZhx| 5.9 High—Temperature Superconductors
S\mh{#Lpk 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
j]YS(Y@AY
5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
O$KLQ '0"n 5.9.3 The Superconducting Gap
6=iz@C7r 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
*Z<`TB)<X 5.9.5 Core—Level Shifts
"*<9)vQ6| 5.10 The Fermi Liquid and the Luttinger Liquid
|tyVC=${ 5.11 Adsorbed Molecules
4s%vx]E 5.11.1 Outline
^Qq_|{vynf 5.11.2 CO on Metal Surfaces
xa ??OT`( References
M"1}"ex# tpU[KR[- 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
a!]'S4JS 6.1 Theory of Photoemission:A Summary of the Three-Step Model
>q"mI6F 6.2 Discussion of the Photocurrent
E]i3E[T 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
eqg|bc[i!t 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
ljQru ^(u 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
j$,:cN 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
5hg:@i',
6.3.1 Band Structure Regime
8-+Ce;h 6.3.2 XPS Regime
KHI-m9( 6.3.3 Surface Emission
r_F\]68 6.3.4 One-Step Calculations
xZwG@+U=X 6.4 Thermal Effects
>2tYw,m 6.5 Dipole Selection Rules for Direct Optical Transitions
3* 1cCM42 References
2ntL7F<ow UBLr|e>dQE 7.Band Structtire and Angular-Resolved Photoelectron Spectra
^cn%]X#. 7.1 Free-Electron Final—State Model
%`?IY < 7.2 Methods Employing Calculated Band Structures
<Y9%oJn% 7.3 Methods for the Absolute Determination of the Crystal Momentum
TY"8.vd 7.3.1 Triangulation or Energy Coincidence Method
a~>+I~^K5q 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
il|e5TD^ 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
Uf4A9$R.G 7.3.4 The Surface Emission Method and Electron Damping
fp^{612O? 7.3.5 The Very-Low-Energy Electron Diffraction Method
TgoaEufS< 7.3.6 The Fermi Surface Method
&s-iie$"@x 7.3.7 Intensities and Their Use in Band-Structure Determinations
I6S!-i 7.3.8 Summary
'1'De^%6W 7.4 Experimental Band Structures
ibAZ=RD 7.4.1 One- and Two-Dimensional Systems
*j6KQZ" 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
db -h=L| 7..4.3UPS Band Structures and XPS Density of States
hSr2<?yk 7.5 A Comment
8iA[w-Pv References
\,&,Q V"K-aO& 8.Surface States, Surface Effects
q!iSY 8.1 Theoretical Considerations
Vsw]v 8.2 Experimental Results on Surface States
]{^'{ z$i 8.3 Quantum-Well States
?71?Vd 8.4 Surface Core-Level Shifts
l1HMH?0| References
G9 v'a& D`d*bNR 9.Inverse Photoelectron Spectroscopy
&6wD 9.1 Surface States
w`KqB(36 9.2 Bulk Band Structures
4&N#d;ErC 9.3 Adsorbed Molecules
PDQEI55 References
kD;1+lNz Bie#GKc 10. Spin-Polarized Photoelectron Spectroscopy
H{M7_1T 10.1 General Description
`xv2,Z9< 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
S1$lNB 10.3 Magnetic Dichroism
Rxb?SBa References
Z uFk}R"x
X} {z7[ 11. Photoelectron Diffraction
X\4d|VJ?m 11.1 Examples
w.X MyHj 11.2 Substrate Photoelectron Diffraction
xbqFek$/r 11.3 Adsorbate Photoelectron Diffraction
/{Mo'.=Z 11.4 Fermi Surface Scans
27J!oin$ References
5-*hAOThg yxk:5L \A Appendix
#
RoJD:9 A.1 Table of Binding Energies
$/p0DY A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
!WSY75 A.3 Compilation of Work Functions
Lh@0|k References
;*u"hIl1/ Index