光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
vtw97G fJK;[*&Y 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
P/,ezVb= %{B4M#~ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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X- P%^mK 2v{42]XYf 目录
?6V U4nK/* 1. Introduction and Basic Principles
(YY!e2 1.1 Historical Development
l{8t;!2t 1.2 The Electron Mean Free Path
#SR )tU 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
FvyC$vip 1.4 Experimental Aspects
%*^s%NI 1.5 Very High Resolution
4hWFgk 1.6 The Theory of Photoemission
c?}{>ig/) 1.6.1 Core-Level Photoemission
7b*9
Th*a 1.6.2 Valence-State Photoemission
p?#xd!tc2N 1.6.3 Three-Step and One-Step Considerations
1[]V @P^ 1.7 Deviations from the Simple Theory of Photoemission
Mi<}q@]e References
S #C;"se ')Qb,#/,% 2. Core Levels and Final States
5|g#>sx>`q 2.1 Core-Level Binding Energies in Atoms and Molecules
asJ t6C 2.1.1 The Equivalent-Core Approximation
GXwQ
)P5] 2.1.2 Chemical Shifts
tN_~zP 2.2 Core-Level Binding Energies in Solids
fiQ/ &]|5 2.2.1 The Born-Haber Cycle in Insulators
$%zM Z 2.2.2 Theory of Binding Energies
2#Y5*r's\ 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
X<uH [ 2.3 Core Polarization
.#_g.0< 2.4 Final-State Multiplets in Rare-Earth Valence Bands
tg;AF<VI 2.5 Vibrational Side Bands
8nTdZu 2.6 Core Levels of Adsorbed Molecules
]//Dd/L6 2.7 Quantitative Chemical Analysis from Core-Level Intensities
=`t%p1 References
i)[~]D.EH8 Z9UNp[0 3. Charge-Excitation Final States: Satellites
n:[LsbTk 3.1 Copper Dihalides; 3d Transition Metal Compounds
@O| lA 3.1.1 Characterization of a Satellite
x?2y^3<5 3.1.2 Analysis of Charge-Transfer Satellites
4~e6z( 3.1.3 Non-local Screening
}b/G{92 3.2 The 6-eV Satellite in Nickel
puK /;nns 3.2.1 Resonance Photoemission
k-8$43 3.2.2 Satellites in Other Metals
fYzZW 3.3 The Gunnarsson-Sch6nhammer Theory
#4{9l
SbU 3.4 Photoemission Signals and Narrow Bands in Metals
2rqYm6 References
Ew2ksZ>B]& cxxrvP- 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
RQW<Sp~ 4.1 Theory
k2DBm q; 4.1.1 General
G;;iGN 4.1.2 Core-Line Shape
F17nWvF 4.1.3 Intrinsic Plasmons
J-Wphc!m 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
}tPI#[cfK 4.1.5 The Total Photoelectron Spectrum
gro@+^DmT 4.2 Experimental Results
?&"!, 4.2.1 The Core Line Without Plasmons
"kkZK=}Nv 4.2.2 Core-Level Spectra Including Plasmoas
bS*oFm@u 4.2.3 Valence-Band Spectra of the Simple Metals
K*oWcsu 4.2.4 Simple Metals: A General Comment
<m+$@:cO 4.3 The Background Correction
Z{
b($po References
>@StKj zP#%ya:I 5. Valence Orbitals in Simple Molecules and Insulating Solids
|d=MX>i|G 5.1 UPS Spectra of Monatomic Gases
)Tj\ym-Vl 5.2 Photoelectron Spectra of Diatomic Molecules
3&7$N#v 5.3 Binding Energy of the H2 Molecule
,XmyC7y< 5.4 Hydrides Isoelectronic with Noble Gases
a[Oi Neon (Ne)
@G0j/@v Hydrogen Fluoride (HF)
+)-`$N Water (H2O)
AV^Sla7|_ Ammonia (NH3)
% yP*Vp,W Methane (CH4)
e X q}0-*f 5.5 Spectra of the Alkali HMides
|T^c(RpOE 5.6 Transition Metal Dihalides
ee{8C~ 5.7 Hydrocarbons
;c;PNihg 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
U#1,]a\ 5.7.2 Linear Polymers
f
iu?mb=* 5.8 Insulating Solids with Valence d Electrons
$.-\2;U 5.8.1 The NiO Problem
psZ #^@>mJ 5.8.2 Mort Insulation
nK5FPFz8 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
Oj^qh+r 5.8.4Band Structures of Transition Metal Compounds
QKtTy>5 5.9 High—Temperature Superconductors
:,BKB*a\ 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
|HMpVT-;j 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
xk$U+8K 5.9.3 The Superconducting Gap
63n<4VSH 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
=)9@rV&~ 5.9.5 Core—Level Shifts
q/HwcX+[b 5.10 The Fermi Liquid and the Luttinger Liquid
8m;tgMFO 5.11 Adsorbed Molecules
$E]WU?U 5.11.1 Outline
%{ToWLb{I 5.11.2 CO on Metal Surfaces
298@&_ References
]M5w!O! Wa+q[E 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
M;K%=l$NG 6.1 Theory of Photoemission:A Summary of the Three-Step Model
&p#$}tm 6.2 Discussion of the Photocurrent
]EZiPW-uy 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
dy^ zOqc 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
_}(ej&'f 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
o7;#B)jWS 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
O$,MdhyXC 6.3.1 Band Structure Regime
BNe6q[ )W~ 6.3.2 XPS Regime
sHQ82uX 6.3.3 Surface Emission
W6 U**ir. 6.3.4 One-Step Calculations
;}k9YlQrN 6.4 Thermal Effects
/"%(i#<)xs 6.5 Dipole Selection Rules for Direct Optical Transitions
k2cC:5Xf3 References
R:t>PFwo v8!Ts" 7.Band Structtire and Angular-Resolved Photoelectron Spectra
`gFE/i18 7.1 Free-Electron Final—State Model
@?r[
$Ea1M 7.2 Methods Employing Calculated Band Structures
3.?kxac 7.3 Methods for the Absolute Determination of the Crystal Momentum
pZg}7F{$ 7.3.1 Triangulation or Energy Coincidence Method
aEW sru 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
e=m=IVY#W 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
^$I8ga 7.3.4 The Surface Emission Method and Electron Damping
QFtf.")[.
7.3.5 The Very-Low-Energy Electron Diffraction Method
^<VJ8jk< 7.3.6 The Fermi Surface Method
F+3}Gkn 7.3.7 Intensities and Their Use in Band-Structure Determinations
n$O[yRMI[ 7.3.8 Summary
k6?;D_dm 7.4 Experimental Band Structures
7A mnxFC 7.4.1 One- and Two-Dimensional Systems
#7}1W[y9}l 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
Ghb Jty` 7..4.3UPS Band Structures and XPS Density of States
awic9uMH 7.5 A Comment
Ob#d;F References
M)JKe!0ad1 6*\WH% 8.Surface States, Surface Effects
exHg<18WSe 8.1 Theoretical Considerations
\6)]!$F6: 8.2 Experimental Results on Surface States
tr t^o 8.3 Quantum-Well States
hmQ;!9 8.4 Surface Core-Level Shifts
Oe/\@f0bLT References
@z-%:J/$ mhDC1lXF 9.Inverse Photoelectron Spectroscopy
.*(xkJI3 9.1 Surface States
%7y8a`} 9.2 Bulk Band Structures
DQy<!Wb+ 9.3 Adsorbed Molecules
8*iIJ References
Y%1 94fY$ zv8AvNDK 10. Spin-Polarized Photoelectron Spectroscopy
(rfR:[JkC2 10.1 General Description
qG<3H!Z!ky 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
NlG~{rfI 10.3 Magnetic Dichroism
f~0CpB*X References
<lo\7p$A dz>2/' 11. Photoelectron Diffraction
p-Jp/*R5 11.1 Examples
3Hd~mfO\ 11.2 Substrate Photoelectron Diffraction
-/'_XR@1 11.3 Adsorbate Photoelectron Diffraction
T{:~v+I= 11.4 Fermi Surface Scans
r&/M')}?Lw References
l3O!{&~K *
",/7( Appendix
]~K&b96( A.1 Table of Binding Energies
f)x(sk A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
. \t8s0A A.3 Compilation of Work Functions
k:QeZn( References
!jTtMx Index