光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
O4^8jK} 8p@Piy{p 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
q(2K6 d\
1Og\U|A 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
9+{G8$Ai OVhE??# &'
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3P^sM1 :=/>Vbd: ) 目录
D-4f > 1. Introduction and Basic Principles
zY('t!u8 1.1 Historical Development
LS88.w\=S@ 1.2 The Electron Mean Free Path
#>mr[ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
Ct=-4 1.4 Experimental Aspects
O2f-5Y$@ 1.5 Very High Resolution
j{9D{ 1.6 The Theory of Photoemission
DIzH`|Y 1.6.1 Core-Level Photoemission
5Drq9B9; 1.6.2 Valence-State Photoemission
+(1zH-^. 1.6.3 Three-Step and One-Step Considerations
WzF !6n!h
1.7 Deviations from the Simple Theory of Photoemission
al9t^ References
w6W}"Uw kT'u1q$3Vo 2. Core Levels and Final States
'-"/ =j&d[ 2.1 Core-Level Binding Energies in Atoms and Molecules
I$0)Px%z 2.1.1 The Equivalent-Core Approximation
UmclTGn 2.1.2 Chemical Shifts
Ndcg/d 2.2 Core-Level Binding Energies in Solids
@ vrV*! 2.2.1 The Born-Haber Cycle in Insulators
P:aJ# 2.2.2 Theory of Binding Energies
jhg;%+KB 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
Yo("U8:XX 2.3 Core Polarization
OC<5E121>Y 2.4 Final-State Multiplets in Rare-Earth Valence Bands
IuRmEL_Q_ 2.5 Vibrational Side Bands
)_i
qAqkS 2.6 Core Levels of Adsorbed Molecules
W>p-u6u%E| 2.7 Quantitative Chemical Analysis from Core-Level Intensities
Jh?dw3Ai^ References
FTQ%JTgT Ts ^"xlK 3. Charge-Excitation Final States: Satellites
yA.4G_|I 3.1 Copper Dihalides; 3d Transition Metal Compounds
- qy6Un+ 3.1.1 Characterization of a Satellite
B&.FOO 3.1.2 Analysis of Charge-Transfer Satellites
*EZHJt9 3.1.3 Non-local Screening
J~1r{5V4{ 3.2 The 6-eV Satellite in Nickel
Ie`13 L2 3.2.1 Resonance Photoemission
)Ib<F7v 3.2.2 Satellites in Other Metals
3+G@g#MY 3.3 The Gunnarsson-Sch6nhammer Theory
'b#0t#|TM 3.4 Photoemission Signals and Narrow Bands in Metals
]b%Hy References
7~GB;1n 3v
mjCm 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
|pmZ.r 4.1 Theory
NLr PSqz 4.1.1 General
VGceD$< 4.1.2 Core-Line Shape
'{J&M|<A 4.1.3 Intrinsic Plasmons
{iv<w8CU) 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
zD(`B+ 4.1.5 The Total Photoelectron Spectrum
1 29q`u; 4.2 Experimental Results
2Ri{bWi 4.2.1 The Core Line Without Plasmons
0\:(ageY? 4.2.2 Core-Level Spectra Including Plasmoas
tX@_fYb 4.2.3 Valence-Band Spectra of the Simple Metals
n[]tXrhU 4.2.4 Simple Metals: A General Comment
??i,Vr@)w 4.3 The Background Correction
p8\zG|b5 References
Wt=| g q}I[N 5. Valence Orbitals in Simple Molecules and Insulating Solids
>j'ZPwj^ 5.1 UPS Spectra of Monatomic Gases
)QG<f{wS 5.2 Photoelectron Spectra of Diatomic Molecules
}yJ$SR]t 5.3 Binding Energy of the H2 Molecule
V\{tmDE 5.4 Hydrides Isoelectronic with Noble Gases
qWx][D" Neon (Ne)
B"v.*
%"&/ Hydrogen Fluoride (HF)
FI<q@HF Water (H2O)
* 0|IXGr Ammonia (NH3)
:LQ5u[g$\ Methane (CH4)
:{ur{m5bX 5.5 Spectra of the Alkali HMides
dpFVN[\oK 5.6 Transition Metal Dihalides
}Y*VAnY6; 5.7 Hydrocarbons
i-'9AYyw 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
:pF_GkG 5.7.2 Linear Polymers
TU GNq 5.8 Insulating Solids with Valence d Electrons
LK;k'IJ 5.8.1 The NiO Problem
4mHvgnT!WA 5.8.2 Mort Insulation
.p=sBLp8 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
+8#_59;x 5.8.4Band Structures of Transition Metal Compounds
-CR?<A4mud 5.9 High—Temperature Superconductors
}4{fQ`HT 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
S_T1y 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
!Mu|mz= 5.9.3 The Superconducting Gap
z9p05NFH 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
J%jB?2
1:o 5.9.5 Core—Level Shifts
2{Chu85 5.10 The Fermi Liquid and the Luttinger Liquid
(C\hVy2X?N 5.11 Adsorbed Molecules
:Mcu 5.11.1 Outline
A^RR@D 5.11.2 CO on Metal Surfaces
\2(SB References
<N`J`J-[ PI~1GyJr@; 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
Qq@G\eRo 6.1 Theory of Photoemission:A Summary of the Three-Step Model
d~?X/sJ t 6.2 Discussion of the Photocurrent
S<L.c 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
h@@nR(<i 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
8NU`^L:1 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
hxf'5uc 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
shH~4<15 6.3.1 Band Structure Regime
O4g+D#Lu 6.3.2 XPS Regime
Bcjx>#3?L 6.3.3 Surface Emission
78Aa|AJU 6.3.4 One-Step Calculations
I"t(%2*q 6.4 Thermal Effects
%&Fk4Z}M 6.5 Dipole Selection Rules for Direct Optical Transitions
'r@:Cz3e*I References
qA:#iJ8w eVR5Xar 7.Band Structtire and Angular-Resolved Photoelectron Spectra
X<MO7I 7.1 Free-Electron Final—State Model
tdEnk.O 7.2 Methods Employing Calculated Band Structures
&I({T`= 7.3 Methods for the Absolute Determination of the Crystal Momentum
x%< 7.3.1 Triangulation or Energy Coincidence Method
2iU7 0(H 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
?hR7<02 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
p:OPw D+ 7.3.4 The Surface Emission Method and Electron Damping
K YkS9_yF 7.3.5 The Very-Low-Energy Electron Diffraction Method
HJC(\\~ 7.3.6 The Fermi Surface Method
\NGC$p n 7.3.7 Intensities and Their Use in Band-Structure Determinations
?|1Mv1C? 7.3.8 Summary
;ml
3 7.4 Experimental Band Structures
X>I)~z}9# 7.4.1 One- and Two-Dimensional Systems
e2+BWKaU 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
6ATtW+sN ] 7..4.3UPS Band Structures and XPS Density of States
/oL;YIoQX 7.5 A Comment
MzYavg` References
7JDN{!jT S|zW^|YU 8.Surface States, Surface Effects
Fa epDjY8 8.1 Theoretical Considerations
7Mx6 8.2 Experimental Results on Surface States
,zQOZ'^ 8.3 Quantum-Well States
%y<ejM 8.4 Surface Core-Level Shifts
\@~UDP]7 References
,WQ^tI=O /U$8TT8+- 9.Inverse Photoelectron Spectroscopy
@+Y8*Rj\3 9.1 Surface States
Pz_NDI 9.2 Bulk Band Structures
0fs$#j 9.3 Adsorbed Molecules
W0zbxJKjd References
d vOJW". d"U(`E=H9 10. Spin-Polarized Photoelectron Spectroscopy
MDRe(rF= 10.1 General Description
f&hwi:t 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
gr-x|wK 10.3 Magnetic Dichroism
%>WbmpIyc References
;U`X 6d .5Q:Xp 11. Photoelectron Diffraction
]feyJLF 11.1 Examples
6e25V4e?I 11.2 Substrate Photoelectron Diffraction
>J=<bhR 11.3 Adsorbate Photoelectron Diffraction
(X6sSO 11.4 Fermi Surface Scans
p{=QGrxB* References
1j\aH&)GH (vJ2z
=z Appendix
8V$3b?] A.1 Table of Binding Energies
3,);0@I A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
pGIe=Um0W A.3 Compilation of Work Functions
15zrrU~D References
^ie^VY($ Index