光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
{4m"S7O EIEq[`h 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
9FLn7Y Po4cbFZ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
TgB;R5 l?1!h2z% jb![ Lp jRkq^} 市场价:¥88.00
pz
IMj_ 优惠价:¥78.60 为您节省:9.40元 (89折)
^[Er%yr0
G\p;
bUF .-Lqo=o\ 目录
YPy))>Q>cK 1. Introduction and Basic Principles
enz Q}^ 1.1 Historical Development
bv4cw#5z$9 1.2 The Electron Mean Free Path
mfN@tMp 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
D5m\u$~V 1.4 Experimental Aspects
r=Q5=(hn 1.5 Very High Resolution
XfrnM^oty 1.6 The Theory of Photoemission
c-=0l)&'D= 1.6.1 Core-Level Photoemission
?^vZ{B)&0E 1.6.2 Valence-State Photoemission
l.W:6",w 1.6.3 Three-Step and One-Step Considerations
wf@2&vJ 1.7 Deviations from the Simple Theory of Photoemission
g[jZ A[[ References
/_a *C.a6 e`Yns$x 2. Core Levels and Final States
qU
n> 2.1 Core-Level Binding Energies in Atoms and Molecules
feW9>f; 2.1.1 The Equivalent-Core Approximation
:Y3?, 2.1.2 Chemical Shifts
g\)z!DQ] 2.2 Core-Level Binding Energies in Solids
"'#Hh&Us 2.2.1 The Born-Haber Cycle in Insulators
pzr-}>xrZ 2.2.2 Theory of Binding Energies
7&)F;;H 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
L>b,}w 2.3 Core Polarization
B~#@fIL 2.4 Final-State Multiplets in Rare-Earth Valence Bands
W8NA. 2.5 Vibrational Side Bands
.Cus t 2.6 Core Levels of Adsorbed Molecules
j[`?`RyU 2.7 Quantitative Chemical Analysis from Core-Level Intensities
~&:R\ References
3Q}Y?rkJ5 ;LE
@Ezx 3. Charge-Excitation Final States: Satellites
OJ 5 !+#> 3.1 Copper Dihalides; 3d Transition Metal Compounds
?$c 3.1.1 Characterization of a Satellite
<Y2!c,"
3.1.2 Analysis of Charge-Transfer Satellites
*~uuCLv_ 3.1.3 Non-local Screening
z0[ZO1Fo( 3.2 The 6-eV Satellite in Nickel
Z5[:Zf?h7J 3.2.1 Resonance Photoemission
[;AcV73 3.2.2 Satellites in Other Metals
AyO|9!F@A 3.3 The Gunnarsson-Sch6nhammer Theory
6{X>9hD 3.4 Photoemission Signals and Narrow Bands in Metals
hob$eWgr References
q)b?X
^ CM1a<bV< 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
J"%}t\Q 4.1 Theory
+:%FJCOT 4.1.1 General
r&sOM_BUF 4.1.2 Core-Line Shape
:Qo 4.1.3 Intrinsic Plasmons
Y`?X Fy: 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
u(Sz$eV 4.1.5 The Total Photoelectron Spectrum
~{G:,|` 4.2 Experimental Results
F:S>\wG, 4.2.1 The Core Line Without Plasmons
CHit
4.2.2 Core-Level Spectra Including Plasmoas
ug"<\" 4.2.3 Valence-Band Spectra of the Simple Metals
veg!mY2& 4.2.4 Simple Metals: A General Comment
!gHWYWu)! 4.3 The Background Correction
<@2# VG References
oD@jtd>b% zxUj1 5. Valence Orbitals in Simple Molecules and Insulating Solids
/+`<X%^U 5.1 UPS Spectra of Monatomic Gases
>wO$Vu
`t 5.2 Photoelectron Spectra of Diatomic Molecules
_i@eOqoC 5.3 Binding Energy of the H2 Molecule
zn1Rou]6 5.4 Hydrides Isoelectronic with Noble Gases
_j\=FJz[ Neon (Ne)
s[@>uP Hydrogen Fluoride (HF)
.4FcZJvy Water (H2O)
*/y]!<\v!k Ammonia (NH3)
S} Cp&}G{P Methane (CH4)
WAXts]= 5.5 Spectra of the Alkali HMides
hUvuq,LH_ 5.6 Transition Metal Dihalides
`Uj?PcS_ 5.7 Hydrocarbons
I''R\Bp 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
/
&D$kxz 5.7.2 Linear Polymers
DbU;jorwu 5.8 Insulating Solids with Valence d Electrons
8{SU?MHQLE 5.8.1 The NiO Problem
Pph8"`mv.m 5.8.2 Mort Insulation
xf"5<PTW</ 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
cgxFEv 5.8.4Band Structures of Transition Metal Compounds
s[2ZxCrCw 5.9 High—Temperature Superconductors
kefv=n*]l 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
=Z .V+ 4+ 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
#lsh N,CPm 5.9.3 The Superconducting Gap
o?mXxL) 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
#t2UPLO~ 5.9.5 Core—Level Shifts
"E)++\JL 5.10 The Fermi Liquid and the Luttinger Liquid
s7nX\:Bw: 5.11 Adsorbed Molecules
795Jwv 5.11.1 Outline
,o@~OTja* 5.11.2 CO on Metal Surfaces
u@_!mjXQ References
=Cy>$/H64 tG2OVRx8u 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
4[,B ;7 6.1 Theory of Photoemission:A Summary of the Three-Step Model
koEX4q 6.2 Discussion of the Photocurrent
lAn+gDP 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
`o8{qU,*]N 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
G</I%qM 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
V l~Y 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
%:w% o$ 6.3.1 Band Structure Regime
]8m_* I! 6.3.2 XPS Regime
fHe0W 6.3.3 Surface Emission
u@Cf*VPK 6.3.4 One-Step Calculations
]r6BLZ[ % 6.4 Thermal Effects
Ur([L& 6.5 Dipole Selection Rules for Direct Optical Transitions
nJ*mEB References
_m7U-;G 33<fN:J]f 7.Band Structtire and Angular-Resolved Photoelectron Spectra
p37zz4 7.1 Free-Electron Final—State Model
oa &z/`@ 7.2 Methods Employing Calculated Band Structures
0i*'N ch#i 7.3 Methods for the Absolute Determination of the Crystal Momentum
+eBMn(7Cgv 7.3.1 Triangulation or Energy Coincidence Method
kUg+I_j6* 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
HLSfoQ&)v 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
6/mkJj+" 7.3.4 The Surface Emission Method and Electron Damping
@UpC{M--Wr 7.3.5 The Very-Low-Energy Electron Diffraction Method
yD[zzEuQ 7.3.6 The Fermi Surface Method
^s2m\Q( 7.3.7 Intensities and Their Use in Band-Structure Determinations
t$H':l0 7.3.8 Summary
@Xve qUUU 7.4 Experimental Band Structures
j(%gMVu 7.4.1 One- and Two-Dimensional Systems
m+Q5vkW 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
Foe>}6~{? 7..4.3UPS Band Structures and XPS Density of States
xA& 7.5 A Comment
nrTv=*tDj References
"B9[cDM& fwi};)K 8.Surface States, Surface Effects
!_U37Uj<m 8.1 Theoretical Considerations
*U;4t/( 8.2 Experimental Results on Surface States
9U|<q 8.3 Quantum-Well States
$bZu^d, 8.4 Surface Core-Level Shifts
qukjS#>+ References
}iua]
4| X(GmiH /E 9.Inverse Photoelectron Spectroscopy
1m>^{u 9.1 Surface States
Vl{~@G, @ 9.2 Bulk Band Structures
aFRTNu/r 9.3 Adsorbed Molecules
|;A9A's References
U#;51_ y@o9~?M 10. Spin-Polarized Photoelectron Spectroscopy
ptV4s=G2 10.1 General Description
{H=oxa 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
x?, ~TC4 10.3 Magnetic Dichroism
zBk_-'z References
tS\=<T Ky[bX 11. Photoelectron Diffraction
"_K}rI6(t 11.1 Examples
${hyNt 11.2 Substrate Photoelectron Diffraction
|H ^w>mk 11.3 Adsorbate Photoelectron Diffraction
klgv{_b 11.4 Fermi Surface Scans
CN.6E<9'kK References
Mn]}s:v / <JY:1| Appendix
j\2]M A.1 Table of Binding Energies
m_Mwg A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
{UB%(E[Mr A.3 Compilation of Work Functions
a(8>n
Z,V References
C
_8j:Z& Index