光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
gCuAF$o d'"r("w# 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
>&U@f #HAC*n 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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"Sridh? v2)g 1sXd ZmEEj-*7s 目录
CnISe^h 1. Introduction and Basic Principles
=0qpVFvU 1.1 Historical Development
{X~gwoz 1.2 The Electron Mean Free Path
IH9.F 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
zMi; A6 1.4 Experimental Aspects
#8XL
:I 1.5 Very High Resolution
#%lo;W~IY 1.6 The Theory of Photoemission
~" i0x 1.6.1 Core-Level Photoemission
aEt/NwgiQ 1.6.2 Valence-State Photoemission
fCWGAO2 1.6.3 Three-Step and One-Step Considerations
=elpH^N 1.7 Deviations from the Simple Theory of Photoemission
PG~$D]; References
2c5-)Dt)T TZR)C P5 2. Core Levels and Final States
O@V%Cu 2.1 Core-Level Binding Energies in Atoms and Molecules
#OO>rm$ 2.1.1 The Equivalent-Core Approximation
#_93f
| 2.1.2 Chemical Shifts
qOih`dla 2.2 Core-Level Binding Energies in Solids
6!'3oN{ 2.2.1 The Born-Haber Cycle in Insulators
}7E^ZZ]f 2.2.2 Theory of Binding Energies
$5D,sEC@ 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
\R36w^c3 2.3 Core Polarization
},+wJ1 2.4 Final-State Multiplets in Rare-Earth Valence Bands
?']5dD 2.5 Vibrational Side Bands
eq(am%3~ 2.6 Core Levels of Adsorbed Molecules
FC i U 2.7 Quantitative Chemical Analysis from Core-Level Intensities
jB{4\) References
m< _S_c S"wR%\NIp 3. Charge-Excitation Final States: Satellites
6KpHnSW 3.1 Copper Dihalides; 3d Transition Metal Compounds
$YN6<5R) 3.1.1 Characterization of a Satellite
X/iT)R]b 3.1.2 Analysis of Charge-Transfer Satellites
Tq]Sn]CSP 3.1.3 Non-local Screening
n2)q}_d 3.2 The 6-eV Satellite in Nickel
vnWWneeNr 3.2.1 Resonance Photoemission
z!l.:F 3.2.2 Satellites in Other Metals
Ut2y;2)a 3.3 The Gunnarsson-Sch6nhammer Theory
0 stc9_O 3.4 Photoemission Signals and Narrow Bands in Metals
sZx/Ee References
IiY/(N+J Y.g59X!Ub2 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
ek#O3Oz 4.1 Theory
0NS<?p~_S 4.1.1 General
xuqv6b. 4.1.2 Core-Line Shape
-r-k_6QP 4.1.3 Intrinsic Plasmons
DRcNdO/1E 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
28 ?\ 4.1.5 The Total Photoelectron Spectrum
5H*\t 7 4.2 Experimental Results
V5UF3'3;} 4.2.1 The Core Line Without Plasmons
a!=D [Gz*5 4.2.2 Core-Level Spectra Including Plasmoas
+j< p
\Kn> 4.2.3 Valence-Band Spectra of the Simple Metals
Tj:B!>> 4.2.4 Simple Metals: A General Comment
*MKO
I' 4.3 The Background Correction
ibj87K References
LDPUD' 59h)-^! 5. Valence Orbitals in Simple Molecules and Insulating Solids
f&Gt| 5.1 UPS Spectra of Monatomic Gases
#1OOU 5.2 Photoelectron Spectra of Diatomic Molecules
y*qVc E 5.3 Binding Energy of the H2 Molecule
8X[:j&@ 5.4 Hydrides Isoelectronic with Noble Gases
_h{C_;a[_ Neon (Ne)
.+$Q<L Hydrogen Fluoride (HF)
PvPOU" Water (H2O)
\NPmym_6J Ammonia (NH3)
'=b/6@& Methane (CH4)
ZrpU <
5.5 Spectra of the Alkali HMides
!|^|,"A) 5.6 Transition Metal Dihalides
F3On?x) 5.7 Hydrocarbons
$a.JSXyxL 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
La`N PY_:> 5.7.2 Linear Polymers
KcWN,!G 5.8 Insulating Solids with Valence d Electrons
<^#,_o,! 5.8.1 The NiO Problem
Z^3rLCa 5.8.2 Mort Insulation
]d$8f 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
h4fJvOk|! 5.8.4Band Structures of Transition Metal Compounds
P3x8UR=fS 5.9 High—Temperature Superconductors
]L5@,E4. 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
XP!S$Q]D 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
em%4Ap 5.9.3 The Superconducting Gap
n(1l}TJy 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
G#ZH.24Y 5.9.5 Core—Level Shifts
ZgTW.<.%2 5.10 The Fermi Liquid and the Luttinger Liquid
kMIcK4.MH 5.11 Adsorbed Molecules
6AAz 5.11.1 Outline
i1 }:8Unxf 5.11.2 CO on Metal Surfaces
*7uH-u"5d References
cN/6SGHK l!D}3jD 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
G30-^Tr 6.1 Theory of Photoemission:A Summary of the Three-Step Model
S|Q@:r" 6.2 Discussion of the Photocurrent
is?{MJZ_ 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
W: z6Koc0 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
m+=] m_ 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
T^zXt? 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
x+\`gK5 6.3.1 Band Structure Regime
Yj&F;_~ 6.3.2 XPS Regime
6fkRrD 6.3.3 Surface Emission
#]\Uk,mhZB 6.3.4 One-Step Calculations
0Um2DjTCG 6.4 Thermal Effects
%Hu5K>ZNYp 6.5 Dipole Selection Rules for Direct Optical Transitions
* `JYC References
D(~U6SR bTI|F]^! 7.Band Structtire and Angular-Resolved Photoelectron Spectra
x'8x
7.1 Free-Electron Final—State Model
CT&|QH{ 7.2 Methods Employing Calculated Band Structures
Z3Og=XHR 7.3 Methods for the Absolute Determination of the Crystal Momentum
9=s<Ld 7.3.1 Triangulation or Energy Coincidence Method
AzPu) 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
v_yw@ 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
%[GsD9_- 7.3.4 The Surface Emission Method and Electron Damping
|NlO7aQ>2H 7.3.5 The Very-Low-Energy Electron Diffraction Method
zOJ%} 7.3.6 The Fermi Surface Method
VMZMG$C 7.3.7 Intensities and Their Use in Band-Structure Determinations
.7J#_*NV 7.3.8 Summary
HVRZ[Y<^ 7.4 Experimental Band Structures
%O;:af"Ja8 7.4.1 One- and Two-Dimensional Systems
X;$+,&M" 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
)+#` CIv 7..4.3UPS Band Structures and XPS Density of States
_O?`@g?i 7.5 A Comment
Y/F6\oh References
KS+'|q<?w 6XxvvMA97 8.Surface States, Surface Effects
#<fRE"v:Q 8.1 Theoretical Considerations
PI {bmZ 8.2 Experimental Results on Surface States
-OV&Md:~ 8.3 Quantum-Well States
KYm0@O>; 8.4 Surface Core-Level Shifts
g _9C* References
<sbu;dQ` -_g0C^:<, 9.Inverse Photoelectron Spectroscopy
iT+8|Yia 9.1 Surface States
AYBns]! 9.2 Bulk Band Structures
b=C*W,Q_# 9.3 Adsorbed Molecules
u,ho7ht3( References
]h`&&B qt bIDj[-CDG 10. Spin-Polarized Photoelectron Spectroscopy
>NV@R& 10.1 General Description
HQdxL*N%^ 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
l\H=m3Bg 10.3 Magnetic Dichroism
s[>,X#7 y References
g/d<Zfq<{ KfEx"94 11. Photoelectron Diffraction
&&8x%Pml 11.1 Examples
\!X8
11.2 Substrate Photoelectron Diffraction
rgQOj^xKv^ 11.3 Adsorbate Photoelectron Diffraction
tKuwpT1Qc 11.4 Fermi Surface Scans
`g?Negt\v References
KK4`l}Fk:n @gEUm_#HTs Appendix
C==hox7b A.1 Table of Binding Energies
B"w?;EeV. A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
~vhE|f A.3 Compilation of Work Functions
fplo w References
6Pnjmw.HV Index