光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
b8h6fB:2 vpP8'f. 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
/rnP/X)T \]qwD m/ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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66'AaA;0^i rp!>rM] s 目录
J\Z\q 1. Introduction and Basic Principles
tRXR/;3O 1.1 Historical Development
vJg^uf) 1.2 The Electron Mean Free Path
bkL5srH 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
V&>mD"~MP 1.4 Experimental Aspects
V3[>^ZCA 1.5 Very High Resolution
bX`VIFc 1.6 The Theory of Photoemission
3M[5_OK 1.6.1 Core-Level Photoemission
Ew2ksZ>B]& 1.6.2 Valence-State Photoemission
_j?/O)M
c 1.6.3 Three-Step and One-Step Considerations
'+iqbcUd, 1.7 Deviations from the Simple Theory of Photoemission
2@f?yh0 References
ILT.yxV |r/4
({n 2. Core Levels and Final States
''wF%q 2.1 Core-Level Binding Energies in Atoms and Molecules
!;.nL-NQ 2.1.1 The Equivalent-Core Approximation
gg QI 2.1.2 Chemical Shifts
?q hme 2.2 Core-Level Binding Energies in Solids
("_tML 8/p 2.2.1 The Born-Haber Cycle in Insulators
fMIKA72>{ 2.2.2 Theory of Binding Energies
Q);^gV 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
22"/|S 2.3 Core Polarization
so }Kb3 n 2.4 Final-State Multiplets in Rare-Earth Valence Bands
[(/IV+ 2.5 Vibrational Side Bands
<m+$@:cO 2.6 Core Levels of Adsorbed Molecules
2w67>w\ 2.7 Quantitative Chemical Analysis from Core-Level Intensities
S<DS|qOo References
Cs8e("w q/^&si 3. Charge-Excitation Final States: Satellites
)Tj\ym-Vl 3.1 Copper Dihalides; 3d Transition Metal Compounds
3&7$N#v 3.1.1 Characterization of a Satellite
P:2 0i*QU 3.1.2 Analysis of Charge-Transfer Satellites
2Ls 3.1.3 Non-local Screening
qY%{c-aMA 3.2 The 6-eV Satellite in Nickel
(ZHEPN 3.2.1 Resonance Photoemission
&HYs^|ydrr 3.2.2 Satellites in Other Metals
"P{T] 3.3 The Gunnarsson-Sch6nhammer Theory
EFS2 zU 3.4 Photoemission Signals and Narrow Bands in Metals
O)9{qU:[b References
VU
8~hF or..e 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
3bPF+(`J 4.1 Theory
Zv)x-48 4.1.1 General
-<.b3M h 4.1.2 Core-Line Shape
J;cTEB 4.1.3 Intrinsic Plasmons
\D,c*I|p7 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
i;8tA! 4.1.5 The Total Photoelectron Spectrum
>$p|W~x 4.2 Experimental Results
QKtTy>5 4.2.1 The Core Line Without Plasmons
:,BKB*a\ 4.2.2 Core-Level Spectra Including Plasmoas
|HMpVT-;j 4.2.3 Valence-Band Spectra of the Simple Metals
xk$U+8K 4.2.4 Simple Metals: A General Comment
63n<4VSH 4.3 The Background Correction
s6J`i&uu References
B&RgUIrFoY #OVf2
" 5. Valence Orbitals in Simple Molecules and Insulating Solids
#iAEcC0k5 5.1 UPS Spectra of Monatomic Gases
V+2C!)f( 5.2 Photoelectron Spectra of Diatomic Molecules
5rx;?yvn 5.3 Binding Energy of the H2 Molecule
B
M$+r(#t 5.4 Hydrides Isoelectronic with Noble Gases
]:vo"{*C Neon (Ne)
01" b9`jU Hydrogen Fluoride (HF)
&?gvW//L2 Water (H2O)
QSq0{ Ammonia (NH3)
.#ASo!O5q Methane (CH4)
,wEcRN w 5.5 Spectra of the Alkali HMides
b 6B5 5.6 Transition Metal Dihalides
CDTM<0`% 5.7 Hydrocarbons
ET 2@dY~ 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
{*J{1)2 5.7.2 Linear Polymers
%\2w
1 5.8 Insulating Solids with Valence d Electrons
[:(^n0% 5.8.1 The NiO Problem
8e3I@mv 5.8.2 Mort Insulation
&KS*rHgt? 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
vMB`TpZ 5.8.4Band Structures of Transition Metal Compounds
eAD uk!Iq 5.9 High—Temperature Superconductors
@fSBW+ 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
V O=
o)H\ 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
QZs ]'*=# 5.9.3 The Superconducting Gap
c$skLz 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
T,D(Xh 5.9.5 Core—Level Shifts
F6\Hqv 5.10 The Fermi Liquid and the Luttinger Liquid
+__PT4ps 5.11 Adsorbed Molecules
c_#+xGS!7 5.11.1 Outline
l@OY8z-_ 5.11.2 CO on Metal Surfaces
H<`<5M 8 References
vz-O2B_u )IH|S5mG? 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
d1rIU6 6.1 Theory of Photoemission:A Summary of the Three-Step Model
:]hNw1e 6.2 Discussion of the Photocurrent
ecRY,MN 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
@ysc?4% q 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
<)dHe: 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
%2jRJ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
%P2l@}?a 6.3.1 Band Structure Regime
]'iOV-2^' 6.3.2 XPS Regime
yHk}'YP 6.3.3 Surface Emission
. h7`Q{ 6.3.4 One-Step Calculations
b&j}f 6.4 Thermal Effects
muJR~4 6.5 Dipole Selection Rules for Direct Optical Transitions
AYP*J References
Adma~]T9 V|n}v?f_q 7.Band Structtire and Angular-Resolved Photoelectron Spectra
_vV3A3|Ec, 7.1 Free-Electron Final—State Model
34gC[G= 7.2 Methods Employing Calculated Band Structures
+-*Ww5Zti 7.3 Methods for the Absolute Determination of the Crystal Momentum
zY=eeG+4s 7.3.1 Triangulation or Energy Coincidence Method
"A]Xe[oS 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
UTLuzm 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
-0>gq$/N=^ 7.3.4 The Surface Emission Method and Electron Damping
qTuQ]*[- 7.3.5 The Very-Low-Energy Electron Diffraction Method
"h'+!2mf 7.3.6 The Fermi Surface Method
Sbp].3^j 7.3.7 Intensities and Their Use in Band-Structure Determinations
~]_U!r[FA 7.3.8 Summary
# zbAA<f 7.4 Experimental Band Structures
.*Mp+Q}^ 7.4.1 One- and Two-Dimensional Systems
D,l&^diz 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
9z$fDs}.q 7..4.3UPS Band Structures and XPS Density of States
&{uj3s&C
7.5 A Comment
<(c_[o/ References
$"P[nNW3 9{KL^O?g 8.Surface States, Surface Effects
<1%(%KdN[ 8.1 Theoretical Considerations
fR$_=WWN>h 8.2 Experimental Results on Surface States
~EL3I 8.3 Quantum-Well States
x,% %^( 8.4 Surface Core-Level Shifts
rn9n _) References
<9bfX 91 [^S(SPL 9.Inverse Photoelectron Spectroscopy
lPyY 9.1 Surface States
6Lb(oY}\3 9.2 Bulk Band Structures
B8~JUGD 9.3 Adsorbed Molecules
ouE/\4'NB References
|Fi{]9(G2 bpx
^ 10. Spin-Polarized Photoelectron Spectroscopy
>2t.7UhDI 10.1 General Description
JuKG#F#, 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
-Is;cbfLj/ 10.3 Magnetic Dichroism
zo|
' References
H-&T) vk0b b3){D 11. Photoelectron Diffraction
'w z6Zt 11.1 Examples
!*1$j7`tP 11.2 Substrate Photoelectron Diffraction
NHL9qL"qk 11.3 Adsorbate Photoelectron Diffraction
Ls`[7w 11.4 Fermi Surface Scans
teKx^ 'c' References
ZccvZl ;b \_]X+o; Appendix
;p+[R+ ) A.1 Table of Binding Energies
bQ3txuha A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
KcvstC` A.3 Compilation of Work Functions
QdrZi.qKH References
21$E.x 6 Index