光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
""dX4^gtU Ul<'@A8 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
f>u{e~Q, Tz=YSQy$9 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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x bG'![OX pvz*(u 目录
.>(?c92 1. Introduction and Basic Principles
'.@'^80iQ 1.1 Historical Development
"hRY+{m 1.2 The Electron Mean Free Path
J.`z;0]op 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
3wS{@' 1.4 Experimental Aspects
F4m Q#YlrS 1.5 Very High Resolution
fs]9H K/@\ 1.6 The Theory of Photoemission
JJvf!] 1.6.1 Core-Level Photoemission
sFEkxZi< 1.6.2 Valence-State Photoemission
cI)XXb4 1.6.3 Three-Step and One-Step Considerations
g5EdW=Dt, 1.7 Deviations from the Simple Theory of Photoemission
XsldbN^6 References
sP0pw]! xHml"Y1 2. Core Levels and Final States
~YIGOL"? 2.1 Core-Level Binding Energies in Atoms and Molecules
N.J;/!%! 2.1.1 The Equivalent-Core Approximation
L`i#yXR 2.1.2 Chemical Shifts
C?n3J 2.2 Core-Level Binding Energies in Solids
CqXD z 2.2.1 The Born-Haber Cycle in Insulators
iL-I#"qT, 2.2.2 Theory of Binding Energies
23/!k}G" 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
\ B~9Ue! 2.3 Core Polarization
K8dlECy 2.4 Final-State Multiplets in Rare-Earth Valence Bands
TA47lz q 2.5 Vibrational Side Bands
qAH@)} 2.6 Core Levels of Adsorbed Molecules
4>4*4!KR} 2.7 Quantitative Chemical Analysis from Core-Level Intensities
8s4y7%,| References
Mk=;UBb$X mm3goIi;Y 3. Charge-Excitation Final States: Satellites
DPfP)J:~ 3.1 Copper Dihalides; 3d Transition Metal Compounds
J&{qe@^ 3.1.1 Characterization of a Satellite
W{OlJRX8 3.1.2 Analysis of Charge-Transfer Satellites
b$sw`Rsw 3.1.3 Non-local Screening
S9Fg0E+J 3.2 The 6-eV Satellite in Nickel
t)o #!)| 3.2.1 Resonance Photoemission
Ejdw"P" 3.2.2 Satellites in Other Metals
-jB1tba 3.3 The Gunnarsson-Sch6nhammer Theory
H|='|k5Y. 3.4 Photoemission Signals and Narrow Bands in Metals
j+3~ References
QZBXI3%#s ~U:{~z 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
:&=TE 2 4.1 Theory
d 7A08l{ 4.1.1 General
EXDtVa Ot 4.1.2 Core-Line Shape
7N^9D
H{` 4.1.3 Intrinsic Plasmons
Y&xmy|O# 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
0fvQPs!O 4.1.5 The Total Photoelectron Spectrum
4#uWj?u 4.2 Experimental Results
6Q,-ZM=Z_p 4.2.1 The Core Line Without Plasmons
^e$;I8l 4.2.2 Core-Level Spectra Including Plasmoas
O6P0Am7s 4.2.3 Valence-Band Spectra of the Simple Metals
v$"#9oh 4.2.4 Simple Metals: A General Comment
B:5(sK 4.3 The Background Correction
\4I1wdd|^ References
!*.mcIQT x^}kG[s 5. Valence Orbitals in Simple Molecules and Insulating Solids
(,PO( 5.1 UPS Spectra of Monatomic Gases
I!.o&dk 5.2 Photoelectron Spectra of Diatomic Molecules
,FX;-nP% 5.3 Binding Energy of the H2 Molecule
1?"vKm 5.4 Hydrides Isoelectronic with Noble Gases
AJSe +1 Neon (Ne)
V'~]b~R Hydrogen Fluoride (HF)
7X.rGJZq Water (H2O)
;A~S){ Ammonia (NH3)
Nh~ Hh( Methane (CH4)
sM({u/ 5.5 Spectra of the Alkali HMides
=,KRZqz 5.6 Transition Metal Dihalides
.pQH>;k]K 5.7 Hydrocarbons
ivC1=+ 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
J&S$F:HM 5.7.2 Linear Polymers
zcD&xoL\H 5.8 Insulating Solids with Valence d Electrons
+vaz gO<u 5.8.1 The NiO Problem
4H8vB^ 5.8.2 Mort Insulation
K+ xiov-r? 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
Wm4@+} 5.8.4Band Structures of Transition Metal Compounds
Dna0M0 5.9 High—Temperature Superconductors
7
2ux3D 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
"JAYTatO7H 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
U?JZ23>bbw 5.9.3 The Superconducting Gap
@jO3+ 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
:Ts"f* 5.9.5 Core—Level Shifts
cBM
A.'uIL 5.10 The Fermi Liquid and the Luttinger Liquid
fM?HZKo 5.11 Adsorbed Molecules
U .hV1 5.11.1 Outline
+ZtqR 5.11.2 CO on Metal Surfaces
U 9TEC) References
ZO{uG(u vL@N21u 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
Bp6jF2 6.1 Theory of Photoemission:A Summary of the Three-Step Model
jDIO,XuF 6.2 Discussion of the Photocurrent
8s pGDg\g 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
1Vt7[L* 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
$n& alcU 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
}9t$Cs% 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
wxVf6` 6.3.1 Band Structure Regime
4m$n Vv 6.3.2 XPS Regime
rA&|!1q"B 6.3.3 Surface Emission
9kL'"0c 6.3.4 One-Step Calculations
2Ch!LS:+ 6.4 Thermal Effects
MBRRzq%F 6.5 Dipole Selection Rules for Direct Optical Transitions
@26H; References
A:ls'MkZ4 &Eg>[gAIlp 7.Band Structtire and Angular-Resolved Photoelectron Spectra
JLm0[1Lzd 7.1 Free-Electron Final—State Model
H7?C>+ay 7.2 Methods Employing Calculated Band Structures
1.!rq,+>1 7.3 Methods for the Absolute Determination of the Crystal Momentum
S9}P5;u 7.3.1 Triangulation or Energy Coincidence Method
P!:Y<p{=> 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
GM|gm-t<@ 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
|Y|{9Osus 7.3.4 The Surface Emission Method and Electron Damping
RS!~5nk5 7.3.5 The Very-Low-Energy Electron Diffraction Method
G*uy@s: 7.3.6 The Fermi Surface Method
lb5Y$ZC 7.3.7 Intensities and Their Use in Band-Structure Determinations
xz[a3In+ 7.3.8 Summary
e@*Gnh<& 7.4 Experimental Band Structures
?Q;8D@
7.4.1 One- and Two-Dimensional Systems
bVSa}&*kM 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
1u75 7..4.3UPS Band Structures and XPS Density of States
J/8aDr(+ 7.5 A Comment
)Xg,;^ References
tKrr5SRb ."l@aE=| 8.Surface States, Surface Effects
;H/*%2 8.1 Theoretical Considerations
B5*{85p(u 8.2 Experimental Results on Surface States
`YAqR?Xj_< 8.3 Quantum-Well States
KG6ki_ 8.4 Surface Core-Level Shifts
rcMVYSj0 References
X+;Ivx 8:0QI kqk 9.Inverse Photoelectron Spectroscopy
>w+WG0Z
K 9.1 Surface States
'm}K$h(U 9.2 Bulk Band Structures
^-cj=on=Q 9.3 Adsorbed Molecules
> xkl7D References
g*F? JDfkm+}uY 10. Spin-Polarized Photoelectron Spectroscopy
)Y}t~ Zfx 10.1 General Description
bPEf2Z
G4 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
zg+78 10.3 Magnetic Dichroism
csz/[* References
/cF
6{0XS9 zm)
]cq 11. Photoelectron Diffraction
]?S\So+ 11.1 Examples
|8PUmax 11.2 Substrate Photoelectron Diffraction
A-1Wn^,>* 11.3 Adsorbate Photoelectron Diffraction
%&5 !vK 11.4 Fermi Surface Scans
\k / N/&; References
lrB@n?hk c<