光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
^Kw&=u xS
H6n 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
^B<PD] {hs2?#p 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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EaM"=g @o4z3Q@ 目录
-+
]T77r 1. Introduction and Basic Principles
8`AcS|k 1.1 Historical Development
+?"HTDBE|| 1.2 The Electron Mean Free Path
(6ohrM>Q 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
mc0sdb,c$ 1.4 Experimental Aspects
5bF9IH 1.5 Very High Resolution
A=v lC?&Z 1.6 The Theory of Photoemission
Y91
e1PsV 1.6.1 Core-Level Photoemission
~J:$gu~` 1.6.2 Valence-State Photoemission
g)Vq5en* 1.6.3 Three-Step and One-Step Considerations
PSP1>-7)w 1.7 Deviations from the Simple Theory of Photoemission
Njy9 JX References
B&%L`v2[ AND7jEn 2. Core Levels and Final States
l#2r.q^$| 2.1 Core-Level Binding Energies in Atoms and Molecules
a gmeiJT 2.1.1 The Equivalent-Core Approximation
aWHd}% 2.1.2 Chemical Shifts
3i]"#wK 2.2 Core-Level Binding Energies in Solids
oglXW8 2.2.1 The Born-Haber Cycle in Insulators
Hl^aUp.c 2.2.2 Theory of Binding Energies
M&|sR+$^ 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
P;)2*:--) 2.3 Core Polarization
S\!
a"0$ 2.4 Final-State Multiplets in Rare-Earth Valence Bands
{+@ms$z 2.5 Vibrational Side Bands
i63`B+L{ 2.6 Core Levels of Adsorbed Molecules
ESC 2.7 Quantitative Chemical Analysis from Core-Level Intensities
6pM"h5hA References
F9m 2C'U [<en1 3. Charge-Excitation Final States: Satellites
_9Dn\=g 3.1 Copper Dihalides; 3d Transition Metal Compounds
Ek"YM[ 3.1.1 Characterization of a Satellite
O_r^oH 3.1.2 Analysis of Charge-Transfer Satellites
O tXw/ 3.1.3 Non-local Screening
T!m42EvIvE 3.2 The 6-eV Satellite in Nickel
E@5zd@[ 3.2.1 Resonance Photoemission
o-\ok|,)#j 3.2.2 Satellites in Other Metals
,X9hl J 3.3 The Gunnarsson-Sch6nhammer Theory
_/8_,9H 3.4 Photoemission Signals and Narrow Bands in Metals
g2[K< References
!6XvvTs/< 4'+d"Ok 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
X0^zw^2W 4.1 Theory
r\A@&5#q 4.1.1 General
Du)B9s 4.1.2 Core-Line Shape
ucQezmie 4.1.3 Intrinsic Plasmons
uHfhRc9 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
3q'K5}
_ 4.1.5 The Total Photoelectron Spectrum
$x;tSJ)m~ 4.2 Experimental Results
+G5'kYzJ 4.2.1 The Core Line Without Plasmons
.Lr`j8 4.2.2 Core-Level Spectra Including Plasmoas
z7'n, [ 4.2.3 Valence-Band Spectra of the Simple Metals
|RHO+J 4.2.4 Simple Metals: A General Comment
=1gDjF9| 4.3 The Background Correction
20
jrv'f References
Am2*- L\QQjI{ 5. Valence Orbitals in Simple Molecules and Insulating Solids
k)$iK2I 5.1 UPS Spectra of Monatomic Gases
!d:tIu{) 5.2 Photoelectron Spectra of Diatomic Molecules
Sp<hai 5.3 Binding Energy of the H2 Molecule
yQu vW$ 5.4 Hydrides Isoelectronic with Noble Gases
NJ
>I%u* Neon (Ne)
GYFgEg} Hydrogen Fluoride (HF)
o8w-$
Qb Water (H2O)
1t0bUf;(M Ammonia (NH3)
re7!p(W?, Methane (CH4)
V[#6yMU @ 5.5 Spectra of the Alkali HMides
Vil@?Y" 5.6 Transition Metal Dihalides
EwTS!gL 5.7 Hydrocarbons
cNdu.c[@ 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
x2sN\tOh^ 5.7.2 Linear Polymers
{&u Rd?( 5.8 Insulating Solids with Valence d Electrons
0w^jls 5.8.1 The NiO Problem
613/K`o 5.8.2 Mort Insulation
xg(<oDn+\ 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
PqTYAN&F 5.8.4Band Structures of Transition Metal Compounds
#uQrJh1o8 5.9 High—Temperature Superconductors
S{o@QVbl 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
K3La9O)> 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
@[n2dmj 5.9.3 The Superconducting Gap
5fU!'ajaN7 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
Jm?l59bv
v 5.9.5 Core—Level Shifts
aZ8h[#]7 5.10 The Fermi Liquid and the Luttinger Liquid
EJO.'vQ 5.11 Adsorbed Molecules
}'u3U"9) 5.11.1 Outline
S*;#'j)4+ 5.11.2 CO on Metal Surfaces
fW(; References
Tsu\oJ[ !&Z*yH 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
:RPVT,O} 6.1 Theory of Photoemission:A Summary of the Three-Step Model
;F|jG}M" 6.2 Discussion of the Photocurrent
$Xf~# uH 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
X )I/%{ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
ggMUdlU 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
}K?F7cD 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
@v"T~6M 6.3.1 Band Structure Regime
`$H7KI G 6.3.2 XPS Regime
6KVV z/ 6.3.3 Surface Emission
b7Yq_%+ 6.3.4 One-Step Calculations
!
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t/ A:k 6.5 Dipole Selection Rules for Direct Optical Transitions
QI.t&sCh5 References
m{VL\ g) !5NGlqEF# 7.Band Structtire and Angular-Resolved Photoelectron Spectra
&/HoSj>HS 7.1 Free-Electron Final—State Model
'wa g |- 7.2 Methods Employing Calculated Band Structures
*`%4loW 7.3 Methods for the Absolute Determination of the Crystal Momentum
<Uf|PFVj$ 7.3.1 Triangulation or Energy Coincidence Method
0xv\D0 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
Yi[4DfA 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
NOV.Bs{
yL 7.3.4 The Surface Emission Method and Electron Damping
"=FIFf 7.3.5 The Very-Low-Energy Electron Diffraction Method
ZHz^S)o\[s 7.3.6 The Fermi Surface Method
YRXK@'[= 7.3.7 Intensities and Their Use in Band-Structure Determinations
vnDmFqelz 7.3.8 Summary
Q^nG0<q+ 7.4 Experimental Band Structures
b"^\)|*4; 7.4.1 One- and Two-Dimensional Systems
&ryiG 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
{JTmP `&l 7..4.3UPS Band Structures and XPS Density of States
v< Ty|(gd 7.5 A Comment
#iiwD| References
8*vFdoE_oO O
/vWd" 8.Surface States, Surface Effects
#T[%6(QW 8.1 Theoretical Considerations
)TM!ms+K 8.2 Experimental Results on Surface States
D_Guc8* 8.3 Quantum-Well States
#o~[1K+Yq 8.4 Surface Core-Level Shifts
h:_NA References
Mg+4huT u9BjgK(M 9.Inverse Photoelectron Spectroscopy
;>5, 9.1 Surface States
lelMt= 9.2 Bulk Band Structures
c+H)ed> 9.3 Adsorbed Molecules
1}`2\3, References
ssPI$IRg! H)\4=^ 10. Spin-Polarized Photoelectron Spectroscopy
<M=';h^w2 10.1 General Description
s_TD4~
$ 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
NfOp=X?Y 10.3 Magnetic Dichroism
) ,yH= 6 References
uC)Zs, _5 #.o0mguU 11. Photoelectron Diffraction
\d:h$ 11.1 Examples
@FU~1u3d 11.2 Substrate Photoelectron Diffraction
A4}#U=3tI 11.3 Adsorbate Photoelectron Diffraction
j|k@MfA 11.4 Fermi Surface Scans
]?M)NRk%S References
kwOeHdV^
A=0@UqM Appendix
?/)lnj)e{ A.1 Table of Binding Energies
j"i#R1T A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
1c/
X A.3 Compilation of Work Functions
YlrB@mE0n$ References
2p+C%"n> Index