光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
u>}w- [ WV@ w 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
l'*^$qc B;Xoa, 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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,3Wb4so J~Cc9"( 目录
rv9B}%e 1. Introduction and Basic Principles
*jk3 \KaoV 1.1 Historical Development
;n`R\NO9 1.2 The Electron Mean Free Path
lPM3}52Xu 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
I|,pE**T 1.4 Experimental Aspects
sm 's-gD 1.5 Very High Resolution
^WE4*.( 1.6 The Theory of Photoemission
0QMTIAW6h 1.6.1 Core-Level Photoemission
X'fuF2owd 1.6.2 Valence-State Photoemission
Z_H?WGO 1.6.3 Three-Step and One-Step Considerations
}]AT _bh, 1.7 Deviations from the Simple Theory of Photoemission
I eG=J4:* References
M|\^UF2e U1ZIuDg'E 2. Core Levels and Final States
JD6aiI!Su 2.1 Core-Level Binding Energies in Atoms and Molecules
x_*%*H 2.1.1 The Equivalent-Core Approximation
fUC9-?(K 2.1.2 Chemical Shifts
G&q'#3ieC 2.2 Core-Level Binding Energies in Solids
8b|OXWl 2.2.1 The Born-Haber Cycle in Insulators
!fY7"E{%% 2.2.2 Theory of Binding Energies
pb!V|#u" 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
z{S:X:X 2.3 Core Polarization
%2f//SZ: 2.4 Final-State Multiplets in Rare-Earth Valence Bands
gtiE hCF2W 2.5 Vibrational Side Bands
lDN"atSf
2.6 Core Levels of Adsorbed Molecules
+l`65!" 2.7 Quantitative Chemical Analysis from Core-Level Intensities
\(I0wEQo$ References
veeI==] .it#`Yz; 3. Charge-Excitation Final States: Satellites
HBH$
3.1 Copper Dihalides; 3d Transition Metal Compounds
5W/{h q8}} 3.1.1 Characterization of a Satellite
|0`hE;Kt7 3.1.2 Analysis of Charge-Transfer Satellites
9 Ycn0 3.1.3 Non-local Screening
q:I$EpKf?Q 3.2 The 6-eV Satellite in Nickel
.evbE O 5 3.2.1 Resonance Photoemission
,P{m k%=9 3.2.2 Satellites in Other Metals
:.kZR; 3.3 The Gunnarsson-Sch6nhammer Theory
j^flwk 3.4 Photoemission Signals and Narrow Bands in Metals
E<>*(x/\e References
o*">KqU`b Ko6^iI1 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
r9#
\13- 4.1 Theory
JK]R*!{n 4.1.1 General
MtS3p>4 4.1.2 Core-Line Shape
e ^Ds 4.1.3 Intrinsic Plasmons
NYwR2oX 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
~@T<gA9V 4.1.5 The Total Photoelectron Spectrum
>nzu],U 4.2 Experimental Results
';0 qj$# 4.2.1 The Core Line Without Plasmons
"13"`!m 4.2.2 Core-Level Spectra Including Plasmoas
w~z[wm Okp 4.2.3 Valence-Band Spectra of the Simple Metals
`ltN,?/ 4.2.4 Simple Metals: A General Comment
&?0:v`4Y 4.3 The Background Correction
*wuqa)q2 References
F>zl9Vi< O~!T3APGU 5. Valence Orbitals in Simple Molecules and Insulating Solids
{`(>O"_[Q 5.1 UPS Spectra of Monatomic Gases
'fx UV<K& 5.2 Photoelectron Spectra of Diatomic Molecules
!d,8kG 5.3 Binding Energy of the H2 Molecule
>@_im6 5.4 Hydrides Isoelectronic with Noble Gases
(hB? Neon (Ne)
1|{bDlmt Hydrogen Fluoride (HF)
'$G"[ljr Water (H2O)
FS6<V0pil Ammonia (NH3)
qH>`}/,P Methane (CH4)
5!I4l1 5.5 Spectra of the Alkali HMides
eSEq{?> 5.6 Transition Metal Dihalides
hA}~es=c 5.7 Hydrocarbons
Ml?~
|_ 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
QzOkpewf 5.7.2 Linear Polymers
/P:.qtT( 5.8 Insulating Solids with Valence d Electrons
a,|?5j9,P 5.8.1 The NiO Problem
x}TS 5.8.2 Mort Insulation
,1oQ cC 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
fpWg R4__ 5.8.4Band Structures of Transition Metal Compounds
!}f1`/ 5.9 High—Temperature Superconductors
~j>D=! 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
{sVY`}p| 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
p5\]5bb 5.9.3 The Superconducting Gap
l[Q:}y 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
)yG"^Ulu 5.9.5 Core—Level Shifts
,](:<A)W& 5.10 The Fermi Liquid and the Luttinger Liquid
^/U27B 5.11 Adsorbed Molecules
Vw tZLP36 5.11.1 Outline
Bc7V)YK 5.11.2 CO on Metal Surfaces
omSM:f_~ References
s 5WqR8 ritBU:6 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
YZc>dE 6.1 Theory of Photoemission:A Summary of the Three-Step Model
{ZU1x C 6.2 Discussion of the Photocurrent
$e1=xSQp4 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
gF?[rqz{ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
oF]cTAqhC. 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
80b;I|-T, 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
O.G'?m<:# 6.3.1 Band Structure Regime
>Dw~POMy 6.3.2 XPS Regime
nDS}^Ba 6.3.3 Surface Emission
);V2?G`/ 6.3.4 One-Step Calculations
_"@CGXu 6.4 Thermal Effects
7 c|bc6? 6.5 Dipole Selection Rules for Direct Optical Transitions
cD*}..-/4 References
dU) ]:>Uz \Ig68dFf% 7.Band Structtire and Angular-Resolved Photoelectron Spectra
!RB)_7 7.1 Free-Electron Final—State Model
b[9&l|y^ 7.2 Methods Employing Calculated Band Structures
mw$r$C{ 7.3 Methods for the Absolute Determination of the Crystal Momentum
K6/@]y%Wr 7.3.1 Triangulation or Energy Coincidence Method
Q?b14]6im 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
Vd^g9 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
uvDzKMw~R 7.3.4 The Surface Emission Method and Electron Damping
fmqb`% 7.3.5 The Very-Low-Energy Electron Diffraction Method
C+[%7vF1 7.3.6 The Fermi Surface Method
r={c,i 7.3.7 Intensities and Their Use in Band-Structure Determinations
;~fT,7qBah 7.3.8 Summary
hu_ ^OlF 7.4 Experimental Band Structures
q<y#pL=k"* 7.4.1 One- and Two-Dimensional Systems
-fhN"B) 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
\B F*m"lz 7..4.3UPS Band Structures and XPS Density of States
>~%e$a7}+ 7.5 A Comment
x:-.+C% References
XU!2YO)t;! n0Y+b[+wj 8.Surface States, Surface Effects
=_$Qtq+h 8.1 Theoretical Considerations
4[Z\
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1b=lpw1} 8.3 Quantum-Well States
W} WI; cI 8.4 Surface Core-Level Shifts
{3;AwhN0H References
`&\Q +W T134ZXqqz 9.Inverse Photoelectron Spectroscopy
8fA_p}wp 9.1 Surface States
Z^ }mp@j> 9.2 Bulk Band Structures
f}g\D#`]/ 9.3 Adsorbed Molecules
+uay(3m(( References
7Q\|=$2 db'/`JeK
b 10. Spin-Polarized Photoelectron Spectroscopy
f#+el
y 10.1 General Description
EY*(Bw 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
*6HTV0jv 10.3 Magnetic Dichroism
l/;X?g5+ References
%ZHP2j
%~ UOQEk22 11. Photoelectron Diffraction
;iDPn2?6?x 11.1 Examples
zJe#m|Z 11.2 Substrate Photoelectron Diffraction
r0p w_j 11.3 Adsorbate Photoelectron Diffraction
d%l{V6 11.4 Fermi Surface Scans
dJ"iEb|4 References
I*9e]m" U(~+o Appendix
V_plq6z A.1 Table of Binding Energies
O=u1u}CP? A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
>S$Z A.3 Compilation of Work Functions
U,nEbKJgk References
GfM;saTz{ Index