光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
R+*-i+]Q#7 =L\&}kzB 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
XQ'$J_hC <@S'vcO 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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53Z[yL jX7;hQ+P 目录
K_Pbzj4(P 1. Introduction and Basic Principles
8kf5u#,' 1.1 Historical Development
j6d{r\!$4 1.2 The Electron Mean Free Path
F2>W{-H+ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
A I v 1.4 Experimental Aspects
M?00n< vM 1.5 Very High Resolution
(j(hr'f 1.6 The Theory of Photoemission
% !>@m6JK 1.6.1 Core-Level Photoemission
e +Ikw1y"f 1.6.2 Valence-State Photoemission
|;(>q 1.6.3 Three-Step and One-Step Considerations
cK- jN9U 1.7 Deviations from the Simple Theory of Photoemission
'kSm}}y References
&s{d r J1R5_b 2. Core Levels and Final States
i'B$Xr 2.1 Core-Level Binding Energies in Atoms and Molecules
{(IHHA> 2.1.1 The Equivalent-Core Approximation
0Of6$` 2.1.2 Chemical Shifts
q:1n=iEi 2.2 Core-Level Binding Energies in Solids
65vsQ|Zw 2.2.1 The Born-Haber Cycle in Insulators
,`8:@<e 2.2.2 Theory of Binding Energies
U
UhlKV|5 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
6o1[fr 2.3 Core Polarization
+V9 (4la 2.4 Final-State Multiplets in Rare-Earth Valence Bands
98maQQWD 2.5 Vibrational Side Bands
cpm *m"Nk 2.6 Core Levels of Adsorbed Molecules
F@KtRUxE 2.7 Quantitative Chemical Analysis from Core-Level Intensities
l>T]Y References
n0FzDQt26 Elt"tJ 3. Charge-Excitation Final States: Satellites
dG!) < 3.1 Copper Dihalides; 3d Transition Metal Compounds
b"2_EnE}1 3.1.1 Characterization of a Satellite
.)E1|U[L 3.1.2 Analysis of Charge-Transfer Satellites
q26qY5D 3.1.3 Non-local Screening
NE><(02qW 3.2 The 6-eV Satellite in Nickel
Eb8~i_B- 3.2.1 Resonance Photoemission
:7*9W|e
3.2.2 Satellites in Other Metals
h05BZrE 3.3 The Gunnarsson-Sch6nhammer Theory
h%5keiA 3.4 Photoemission Signals and Narrow Bands in Metals
~uG/F?= Q: References
g'9~T8i& ^ \"X_zM 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
yuhY )T 4.1 Theory
JF'<"" 4.1.1 General
HOr Xxxp1^ 4.1.2 Core-Line Shape
I :8s 3; 4.1.3 Intrinsic Plasmons
[[O4_)?el 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
}&]T0U`@ 4.1.5 The Total Photoelectron Spectrum
7e[&hea 4.2 Experimental Results
I0N~>SpZ5 4.2.1 The Core Line Without Plasmons
hb(H-`16 4.2.2 Core-Level Spectra Including Plasmoas
)K]<\Q[ 4.2.3 Valence-Band Spectra of the Simple Metals
|+Xh ^E 4.2.4 Simple Metals: A General Comment
4j(*%da 4.3 The Background Correction
FjW%M;H References
mln%Rd6u/ _z\qtl~3 5. Valence Orbitals in Simple Molecules and Insulating Solids
'8LHX6FXK 5.1 UPS Spectra of Monatomic Gases
L+lX$k 5.2 Photoelectron Spectra of Diatomic Molecules
w6ck wn, 5.3 Binding Energy of the H2 Molecule
0S\HO<~k 5.4 Hydrides Isoelectronic with Noble Gases
_`Dz%(c Neon (Ne)
yQq|!'MK k Hydrogen Fluoride (HF)
sfp.> bMj Water (H2O)
\Hu?K\SWs Ammonia (NH3)
)h,}v()qc# Methane (CH4)
"2:#bXM- 5.5 Spectra of the Alkali HMides
1i#U& 5.6 Transition Metal Dihalides
g@m__ 5.7 Hydrocarbons
WV;[v g] 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
?SX0e(+}} 5.7.2 Linear Polymers
<U}25AR 5.8 Insulating Solids with Valence d Electrons
7'7o^>
! 5.8.1 The NiO Problem
3=_to7] 5.8.2 Mort Insulation
{sUc2vR 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
^ lG^. 5.8.4Band Structures of Transition Metal Compounds
YVO~0bX: 5.9 High—Temperature Superconductors
\r}*<CRr6 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
LufZ, 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
Mvk#$:8e 5.9.3 The Superconducting Gap
a61?G!] 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
OKCX>'j:S 5.9.5 Core—Level Shifts
ROj=XM:+ 5.10 The Fermi Liquid and the Luttinger Liquid
2'WdH1UrBc 5.11 Adsorbed Molecules
tp b(.`G 5.11.1 Outline
^ |>)H 5.11.2 CO on Metal Surfaces
{'Gu@l References
ScC!?rTW~7 9-?kamA 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
6K5KkEp 6.1 Theory of Photoemission:A Summary of the Three-Step Model
Of{'A 6.2 Discussion of the Photocurrent
;W!hl<``d* 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
gC/-7/} 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
NAfu$7 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
W97
&[([ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
pl.=u0 * 6.3.1 Band Structure Regime
R(HW0@R@w 6.3.2 XPS Regime
:w4I+*] 6.3.3 Surface Emission
JmVha!<qk 6.3.4 One-Step Calculations
|Vc:o_n7 6.4 Thermal Effects
CYC6:g|) 6.5 Dipole Selection Rules for Direct Optical Transitions
WR>2t&;E References
kN$L8U8f l7GLN1#m 7.Band Structtire and Angular-Resolved Photoelectron Spectra
mQt?d?6 7.1 Free-Electron Final—State Model
XcQ'( 7.2 Methods Employing Calculated Band Structures
,6a }l;lv 7.3 Methods for the Absolute Determination of the Crystal Momentum
E%>){Y) 7.3.1 Triangulation or Energy Coincidence Method
FZtILlw 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
|y7#D9m 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
;AgXl%Q 7.3.4 The Surface Emission Method and Electron Damping
L QP4#7 7.3.5 The Very-Low-Energy Electron Diffraction Method
o8S)8_3 7.3.6 The Fermi Surface Method
~TALpd 7.3.7 Intensities and Their Use in Band-Structure Determinations
0)3*E)g{ 7.3.8 Summary
]6EXaf# 7.4 Experimental Band Structures
@T+pQ)0{{ 7.4.1 One- and Two-Dimensional Systems
\)T4NN 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
%Tv^BYQAZ 7..4.3UPS Band Structures and XPS Density of States
[+v}V ,jb 7.5 A Comment
%+Khj@aX References
=9vmRh?8 xo*[
g`N 8.Surface States, Surface Effects
b."1p7' 8.1 Theoretical Considerations
z|>f*Z 8.2 Experimental Results on Surface States
&\o!-EIK8 8.3 Quantum-Well States
)|@UY(VZ^ 8.4 Surface Core-Level Shifts
nLjo3yvV.. References
T5di#%: s Y+I`XeY 9.Inverse Photoelectron Spectroscopy
6~v|pA jY 9.1 Surface States
Sud5F4S 9.2 Bulk Band Structures
l~Sn`%PgA 9.3 Adsorbed Molecules
U0W- X9>y References
}n JG<rY JMq00_ 10. Spin-Polarized Photoelectron Spectroscopy
O~AOZ^a:2 10.1 General Description
7|Tu@0XXA 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
yjP;o`z% 10.3 Magnetic Dichroism
(PN!k0Y References
KI="O6 h #5x[Z[m 11. Photoelectron Diffraction
S?_ ;$Cn 11.1 Examples
sx0:g?F3j 11.2 Substrate Photoelectron Diffraction
Tfl4MDZb 11.3 Adsorbate Photoelectron Diffraction
yegTKoY 11.4 Fermi Surface Scans
(_ElM> References
KwiTnP!Dca L_YVe(dT Appendix
6 4da~SEn A.1 Table of Binding Energies
O2Mo ~} A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
N5=;
PZub A.3 Compilation of Work Functions
nEM>*;iE References
8PV`4=,OI Index