光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
>_xuXEslUz %.D!J",\/K 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
o<iU;15 !yVY[ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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_yUYEq<` s*_fRf: 目录
UPP"-`t 1. Introduction and Basic Principles
QxA( *1 1.1 Historical Development
(hdu+^Qj= 1.2 The Electron Mean Free Path
~bm'i%$k 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
oPF]]Imu 1.4 Experimental Aspects
7i{(,: 1.5 Very High Resolution
VH~YwO!x 1.6 The Theory of Photoemission
b- e 1.6.1 Core-Level Photoemission
oGB|k]6]| 1.6.2 Valence-State Photoemission
<xF]ca 1.6.3 Three-Step and One-Step Considerations
:fwt PvLo 1.7 Deviations from the Simple Theory of Photoemission
|dbKK\ X9 References
\o/eF& ;Vc|3 2. Core Levels and Final States
uDXV@;6< 2.1 Core-Level Binding Energies in Atoms and Molecules
4bp})>}jB 2.1.1 The Equivalent-Core Approximation
oQ,<Yx%E3 2.1.2 Chemical Shifts
H8[A*uYL
2.2 Core-Level Binding Energies in Solids
4oH ,_sr 2.2.1 The Born-Haber Cycle in Insulators
})P!7t 2.2.2 Theory of Binding Energies
[`qdpzUp& 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
0+ $gR~^^ 2.3 Core Polarization
d"miPR 2.4 Final-State Multiplets in Rare-Earth Valence Bands
kE.4 # 2.5 Vibrational Side Bands
GM'yOJo 2.6 Core Levels of Adsorbed Molecules
K)wWqC. 2.7 Quantitative Chemical Analysis from Core-Level Intensities
T]Ai{@i References
!&hqj$>-} J{prI;]K 3. Charge-Excitation Final States: Satellites
<$zhNu~ 3.1 Copper Dihalides; 3d Transition Metal Compounds
jLt3jN 3.1.1 Characterization of a Satellite
![_0GFbT 3.1.2 Analysis of Charge-Transfer Satellites
MjQju@ 3.1.3 Non-local Screening
pvUV5^B(M 3.2 The 6-eV Satellite in Nickel
-,b+tC<V)0 3.2.1 Resonance Photoemission
!rr,(!Ip?O 3.2.2 Satellites in Other Metals
M*ZN]9{^. 3.3 The Gunnarsson-Sch6nhammer Theory
q)Nw$dW< 3.4 Photoemission Signals and Narrow Bands in Metals
aK
-x{ References
B+U:=591 ^7gKs2M 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
oC49c~`8 4.1 Theory
1u7D:h># 4.1.1 General
|,:p[Oy 4.1.2 Core-Line Shape
8$A0q%n 4.1.3 Intrinsic Plasmons
_Iav2=0Wi 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
]q{_i 4.1.5 The Total Photoelectron Spectrum
1J/'R37lP 4.2 Experimental Results
e
}?.3,? 4.2.1 The Core Line Without Plasmons
Vi-Ph;6[ 4.2.2 Core-Level Spectra Including Plasmoas
l7qW)<r 4.2.3 Valence-Band Spectra of the Simple Metals
mu@ J$\
4.2.4 Simple Metals: A General Comment
HrvyI)4{ 4.3 The Background Correction
(~zu4^9w References
` qs}L ;[R6rVHe{ 5. Valence Orbitals in Simple Molecules and Insulating Solids
j\~,Gtn>Z 5.1 UPS Spectra of Monatomic Gases
o4WQA"VxM 5.2 Photoelectron Spectra of Diatomic Molecules
>bze0`}Z 5.3 Binding Energy of the H2 Molecule
_8u TK%| 5.4 Hydrides Isoelectronic with Noble Gases
Wy7w zt Neon (Ne)
4BCe;Q^6 Hydrogen Fluoride (HF)
iLuC_.'u= Water (H2O)
2.niB> Ammonia (NH3)
MlWKfe< Methane (CH4)
;b [>{Q; 5.5 Spectra of the Alkali HMides
bnfeZR1m_ 5.6 Transition Metal Dihalides
-`q!mdA2 5.7 Hydrocarbons
|gA@$1+} 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
rmw}Ui" 5.7.2 Linear Polymers
@~2k5pa 5.8 Insulating Solids with Valence d Electrons
mfZbo#KS#v 5.8.1 The NiO Problem
3|$?T|#B 5.8.2 Mort Insulation
P7}w^#x 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
:j+E]|d(~6 5.8.4Band Structures of Transition Metal Compounds
|E K6txRb 5.9 High—Temperature Superconductors
3)VO{Cj! 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
c= 2E/x? 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
9'p| [?]v 5.9.3 The Superconducting Gap
+jrx;xwot 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
`P\H{ 5.9.5 Core—Level Shifts
;,U@zB;\%( 5.10 The Fermi Liquid and the Luttinger Liquid
pu MVvo 5.11 Adsorbed Molecules
3\ajnd| 5.11.1 Outline
?T73BL= 5.11.2 CO on Metal Surfaces
]Yt3@ug_f References
'dwsm7Xd _~Od G 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
z]g#2xD2 6.1 Theory of Photoemission:A Summary of the Three-Step Model
[uqr 6.2 Discussion of the Photocurrent
FsUH/Y
y 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
'(r?($s 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
h(q4
B~ 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
;,Vdj[W$> 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
f|~'(~Sr 6.3.1 Band Structure Regime
d3E N0e+^ 6.3.2 XPS Regime
j\KOKvY) 6.3.3 Surface Emission
hlyh8=Z6o 6.3.4 One-Step Calculations
GX19GI@k 6.4 Thermal Effects
3 a(SmM: 6.5 Dipole Selection Rules for Direct Optical Transitions
t#M[w|5? References
MV<)qa T :D}?H@(69 7.Band Structtire and Angular-Resolved Photoelectron Spectra
7]u_ 7.1 Free-Electron Final—State Model
2O(k@M5E? 7.2 Methods Employing Calculated Band Structures
TS=%iMa 7.3 Methods for the Absolute Determination of the Crystal Momentum
gz'{l[ 7.3.1 Triangulation or Energy Coincidence Method
XH0{|#hwN 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
si%V63 ^lN 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
.))k 7.3.4 The Surface Emission Method and Electron Damping
Fc=F2M o? 7.3.5 The Very-Low-Energy Electron Diffraction Method
B7A.~'= 7.3.6 The Fermi Surface Method
$hJ 4=F 7.3.7 Intensities and Their Use in Band-Structure Determinations
X%!?\3S 7.3.8 Summary
3|e~YmZx 7.4 Experimental Band Structures
\Q`#E'? 7.4.1 One- and Two-Dimensional Systems
BB,-HhYT0 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
78T;b7!-C 7..4.3UPS Band Structures and XPS Density of States
aG" 7.5 A Comment
MAqETjB References
p^{yA"MQ /q]fG 8.Surface States, Surface Effects
-[=@'NP 8.1 Theoretical Considerations
S]ndnxy"b 8.2 Experimental Results on Surface States
^l(,'>Cn 8.3 Quantum-Well States
L(y~
,Kc 8.4 Surface Core-Level Shifts
K:4G(?w References
V!e`P 4`CO>Q 9.Inverse Photoelectron Spectroscopy
qyE*?73W 9.1 Surface States
ciHTnC 9.2 Bulk Band Structures
i+-=I+L3 9.3 Adsorbed Molecules
MmfshnTN References
qqYQ/4Ajw u 8~5e 10. Spin-Polarized Photoelectron Spectroscopy
s0Y7`uD^ 10.1 General Description
C`oB [ 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
a<pEVV\NB~ 10.3 Magnetic Dichroism
iee`Yg!EOH References
Y% [H: ,;=
S\ 11. Photoelectron Diffraction
@bFl8- 11.1 Examples
9zehwl]~ 11.2 Substrate Photoelectron Diffraction
HRd02tah 11.3 Adsorbate Photoelectron Diffraction
f`J[u!Ja 11.4 Fermi Surface Scans
IgF#f%|Q References
\iwUsv>SB w/0;N`YB Appendix
A.P*@}9 A.1 Table of Binding Energies
n
u>6UjV A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
-fz( ]d A.3 Compilation of Work Functions
RoD9 References
su=]gE@ Index