光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
%^BOYvPx lfG&V +S1 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
SCC/
<o z Clm'X/ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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3cQmxp2* ue2nfp 目录
}U1{&4Ph 1. Introduction and Basic Principles
H[yLlv 1.1 Historical Development
-m-WUox4" 1.2 The Electron Mean Free Path
1;9E*= 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
:fQ*'m, 1.4 Experimental Aspects
B_G7F[/K 1.5 Very High Resolution
oU6g5 1.6 The Theory of Photoemission
fmyS#
6" 1.6.1 Core-Level Photoemission
]$*_2V3VA$ 1.6.2 Valence-State Photoemission
.-*nD8b 1.6.3 Three-Step and One-Step Considerations
+*~3"ww< 1.7 Deviations from the Simple Theory of Photoemission
1j-i nj` References
/JYi^rZ im\Ws./ 2. Core Levels and Final States
N8Q{4c 2.1 Core-Level Binding Energies in Atoms and Molecules
gVWLY;c 3} 2.1.1 The Equivalent-Core Approximation
4vJIO{m 2.1.2 Chemical Shifts
c8W=Is` 2.2 Core-Level Binding Energies in Solids
spDRQ_qq 2.2.1 The Born-Haber Cycle in Insulators
RH 0a\RC!G 2.2.2 Theory of Binding Energies
a"N_zGf2$ 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
No+zw% l0E 2.3 Core Polarization
aDEP_b; 2.4 Final-State Multiplets in Rare-Earth Valence Bands
?':'zT 2.5 Vibrational Side Bands
:CHd\."%+1 2.6 Core Levels of Adsorbed Molecules
^(B*AE. 2.7 Quantitative Chemical Analysis from Core-Level Intensities
>QPS0Vx[ References
:S2MS{>Mo /!3:K<6@ 3. Charge-Excitation Final States: Satellites
X;g|-< 3.1 Copper Dihalides; 3d Transition Metal Compounds
)&-+:u0 3.1.1 Characterization of a Satellite
06O 3.1.2 Analysis of Charge-Transfer Satellites
(9%%^s]uPT 3.1.3 Non-local Screening
zYJxoC{ 3.2 The 6-eV Satellite in Nickel
Fje%hcV 3.2.1 Resonance Photoemission
r4zS, J;, 3.2.2 Satellites in Other Metals
Kj5f:{Ur 3.3 The Gunnarsson-Sch6nhammer Theory
?uv%E*TU 3.4 Photoemission Signals and Narrow Bands in Metals
}_TdXY
#w\ References
)QT+;P. 3E9j%sYk 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
ShxX[k 4.1 Theory
V&85<Y%Nl| 4.1.1 General
/y@iaptC 4.1.2 Core-Line Shape
=Q/i<u 4.1.3 Intrinsic Plasmons
Wn5]2D\vkT 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
^5F/=TtE G 4.1.5 The Total Photoelectron Spectrum
548BM^^"r 4.2 Experimental Results
85]UrwlA4 4.2.1 The Core Line Without Plasmons
@x4Dt&:" 4.2.2 Core-Level Spectra Including Plasmoas
|+''d 4.2.3 Valence-Band Spectra of the Simple Metals
{F[Xe_=#" 4.2.4 Simple Metals: A General Comment
N<%,3W_-_ 4.3 The Background Correction
R~([ References
64@s|m* 6Rj
X 5. Valence Orbitals in Simple Molecules and Insulating Solids
+UtK2<^:o 5.1 UPS Spectra of Monatomic Gases
tp&iOP6O 5.2 Photoelectron Spectra of Diatomic Molecules
,)G,[ih 5.3 Binding Energy of the H2 Molecule
`$HO`d@0*R 5.4 Hydrides Isoelectronic with Noble Gases
rG6/h'!| Neon (Ne)
p
IToy;] Hydrogen Fluoride (HF)
RB!E>] Water (H2O)
L&%iY7sC` Ammonia (NH3)
+V^_ksi\ Methane (CH4)
.}wir, 5.5 Spectra of the Alkali HMides
Yn/-m
Z 5.6 Transition Metal Dihalides
8!fwXm 5.7 Hydrocarbons
kzu=-@s 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
:W"ITY( 5.7.2 Linear Polymers
?9cy5z[ 5.8 Insulating Solids with Valence d Electrons
NGu]|p 5.8.1 The NiO Problem
u1l#k60 5.8.2 Mort Insulation
q)X&S*-<o~ 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
C'#:}]@E 5.8.4Band Structures of Transition Metal Compounds
;iVyJZI 5.9 High—Temperature Superconductors
G 2##M8:U0 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
ikC;N5Sw 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
CDhk!O.. 5.9.3 The Superconducting Gap
%qMk&1
5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
\kx9V|A' 5.9.5 Core—Level Shifts
n>'}tT)U 5.10 The Fermi Liquid and the Luttinger Liquid
QG.FW;/L, 5.11 Adsorbed Molecules
<G={Vfr 5.11.1 Outline
hT[O5
5.11.2 CO on Metal Surfaces
5h&8!!$[ References
t@\0$V
\X 9TLP( 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
o<y7Ut 6.1 Theory of Photoemission:A Summary of the Three-Step Model
pH%K4bV)8 6.2 Discussion of the Photocurrent
5ym
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'JydaF~> 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
827N?pU$) 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
:BS`Q/<w 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
:
SNp"| 6.3.1 Band Structure Regime
z3,z&Ra 6.3.2 XPS Regime
4{V=X3,x 6.3.3 Surface Emission
/dAIg1ra 6.3.4 One-Step Calculations
@({65 gJ* 6.4 Thermal Effects
chy7hPxC; 6.5 Dipole Selection Rules for Direct Optical Transitions
3HD=)k References
> 01k
u ZHT.+X:_ 7.Band Structtire and Angular-Resolved Photoelectron Spectra
Kf*+Ilq%L 7.1 Free-Electron Final—State Model
Lqt] 7.2 Methods Employing Calculated Band Structures
kF?\p`[a 7.3 Methods for the Absolute Determination of the Crystal Momentum
AbB%osz}Ed 7.3.1 Triangulation or Energy Coincidence Method
XX =A1#H 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
I?=Q
*og 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
F n\)*; ^ 7.3.4 The Surface Emission Method and Electron Damping
8r5j~Df 7.3.5 The Very-Low-Energy Electron Diffraction Method
w*?JW 7.3.6 The Fermi Surface Method
+Fk.B@KT, 7.3.7 Intensities and Their Use in Band-Structure Determinations
s<myZ T$ 7.3.8 Summary
F=cO=5Iz 7.4 Experimental Band Structures
6i%)'dl 7.4.1 One- and Two-Dimensional Systems
Kxg09\5i 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
Gh j[nsoC~ 7..4.3UPS Band Structures and XPS Density of States
P_9O8"W 7.5 A Comment
'uh6?2)wG References
v^vEaB 83@+X4ptp 8.Surface States, Surface Effects
E7N1B*KI 8.1 Theoretical Considerations
q
o'1Pknz 8.2 Experimental Results on Surface States
T"$"`A" 8.3 Quantum-Well States
`O[M#y%*E 8.4 Surface Core-Level Shifts
m2_B(- References
LWY`J0/ ~
60J 9.Inverse Photoelectron Spectroscopy
{w2<;YXj! 9.1 Surface States
bz@4obRqf 9.2 Bulk Band Structures
:Z<-J` 9.3 Adsorbed Molecules
6d_l[N References
`=oN &! 8g<3J-7Mm 10. Spin-Polarized Photoelectron Spectroscopy
RAe:$Iv$!v 10.1 General Description
"UE'dWz 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
ydpsPU?wj5 10.3 Magnetic Dichroism
~q<UE\H References
_9<Ko.GVq c1c0b|B!U 11. Photoelectron Diffraction
DJeG 11.1 Examples
A w83@U 11.2 Substrate Photoelectron Diffraction
^K3{6}] 11.3 Adsorbate Photoelectron Diffraction
vHWw*gg(/E 11.4 Fermi Surface Scans
gbF.Q7?$u References
)=~1m85+5B |g@1qXO3 Appendix
=_,w< A.1 Table of Binding Energies
$"sf%{~ A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
klPc l[.w A.3 Compilation of Work Functions
/QTGZb References
mgS%YG Index