光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
WH'[~O hEEbH@b 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
,gRsbC +gT?{;3[i 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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7EO%, }HXNhv-K 目录
/<y-pFTg 1. Introduction and Basic Principles
ZEHz/Y% 1.1 Historical Development
wRU pQ~=B2 1.2 The Electron Mean Free Path
M[Ls:\1a 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
i mJ{wF 1.4 Experimental Aspects
w9z((\5 1.5 Very High Resolution
[Ma&=2h 1.6 The Theory of Photoemission
|QxDjL<&t4 1.6.1 Core-Level Photoemission
\!s0VEE 1.6.2 Valence-State Photoemission
t5e% "}>7H 1.6.3 Three-Step and One-Step Considerations
J}<k`af 1.7 Deviations from the Simple Theory of Photoemission
#9p{Y}2# References
%.[GR !XgkK k 2. Core Levels and Final States
9I9J}&4 2.1 Core-Level Binding Energies in Atoms and Molecules
R+, tn,<< 2.1.1 The Equivalent-Core Approximation
,R*ru* 2.1.2 Chemical Shifts
qTiX;e\W 2.2 Core-Level Binding Energies in Solids
WvNX%se]3 2.2.1 The Born-Haber Cycle in Insulators
/[_>U{~P# 2.2.2 Theory of Binding Energies
<W\~A$ 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
tQ] R@i 2.3 Core Polarization
~vaV=}) 2.4 Final-State Multiplets in Rare-Earth Valence Bands
q6/ o.j 2.5 Vibrational Side Bands
lusINILc 2.6 Core Levels of Adsorbed Molecules
H}JH339 2.7 Quantitative Chemical Analysis from Core-Level Intensities
"S)4Cjk References
/1Rm^s)2z UZ&bT'>;9g 3. Charge-Excitation Final States: Satellites
q4(&.Al\@ 3.1 Copper Dihalides; 3d Transition Metal Compounds
E%jOJA 3.1.1 Characterization of a Satellite
vZ$uD,@;. 3.1.2 Analysis of Charge-Transfer Satellites
~])\xC 3.1.3 Non-local Screening
Y@RPQPmIQ 3.2 The 6-eV Satellite in Nickel
D='/-3f!F] 3.2.1 Resonance Photoemission
RH>b, 3.2.2 Satellites in Other Metals
c9iCH~ 3.3 The Gunnarsson-Sch6nhammer Theory
IN`05 Q 3.4 Photoemission Signals and Narrow Bands in Metals
l0[jepmpiT References
WynHcxC "D8xHHb 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
u[PO'6Kzd 4.1 Theory
>y%$]0F1 4.1.1 General
U}7$:hO"dX 4.1.2 Core-Line Shape
#Rjm3#gc 4.1.3 Intrinsic Plasmons
vF3>nN(] 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
42tD$S5^ 4.1.5 The Total Photoelectron Spectrum
A$fd6+{ 4.2 Experimental Results
LK/gG6n5M0 4.2.1 The Core Line Without Plasmons
kzgHp,;R{ 4.2.2 Core-Level Spectra Including Plasmoas
#y}@FG 4.2.3 Valence-Band Spectra of the Simple Metals
/]<0`nI. 4.2.4 Simple Metals: A General Comment
eJ$?T7aUf 4.3 The Background Correction
D@5&xd_@4 References
tCtR(mG=A Zdj~B1 5. Valence Orbitals in Simple Molecules and Insulating Solids
#qm<4]91 5.1 UPS Spectra of Monatomic Gases
IS]0 3_uQ 5.2 Photoelectron Spectra of Diatomic Molecules
W{ @lt} 5.3 Binding Energy of the H2 Molecule
Vg6?a 5.4 Hydrides Isoelectronic with Noble Gases
q.~.1
'`! Neon (Ne)
8p>%}LX/ Hydrogen Fluoride (HF)
mkrvWZjZX Water (H2O)
X#1So .}c Ammonia (NH3)
241YJ Methane (CH4)
,t61IU3" 5.5 Spectra of the Alkali HMides
`k_5Pz\ 5.6 Transition Metal Dihalides
Nki18ud# 5.7 Hydrocarbons
noh3mi 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
pRUN[[L 5.7.2 Linear Polymers
{eqUEdC 5.8 Insulating Solids with Valence d Electrons
f9&D0x? 5.8.1 The NiO Problem
./J.OU1 5.8.2 Mort Insulation
J0mY=vX 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
fcD$km 5.8.4Band Structures of Transition Metal Compounds
1}KNzMHk9 5.9 High—Temperature Superconductors
<74q]C 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
z`>a,X 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
zUIh8cAoE 5.9.3 The Superconducting Gap
-md2Z0^ Kc 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
ch
\*/ 5.9.5 Core—Level Shifts
eey <:n/Z 5.10 The Fermi Liquid and the Luttinger Liquid
QVn!60[lj 5.11 Adsorbed Molecules
/M v\~vg$1 5.11.1 Outline
T*-*U/ 5.11.2 CO on Metal Surfaces
`
n@[=l~ References
!ssE >bDa g%1!YvS3v 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
!*?&V3! 6.1 Theory of Photoemission:A Summary of the Three-Step Model
u0w2v+ 6.2 Discussion of the Photocurrent
V*U"OJ% 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
hLYSYMUb 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
5}e-\:J>B 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
~W%A8`9 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
Q:>;d-D|1 6.3.1 Band Structure Regime
3f
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WI[6l6 6.3.3 Surface Emission
:4]&R9J>o 6.3.4 One-Step Calculations
pc:K5 -Os 6.4 Thermal Effects
H6bomp" 6.5 Dipole Selection Rules for Direct Optical Transitions
<uu1e@P References
x #BUIi '[`.&-; 7.Band Structtire and Angular-Resolved Photoelectron Spectra
hY-;Wfg 7.1 Free-Electron Final—State Model
QRgWzaI 7.2 Methods Employing Calculated Band Structures
jWUN~#p! 7.3 Methods for the Absolute Determination of the Crystal Momentum
7{v0K"E{ 7.3.1 Triangulation or Energy Coincidence Method
Q%o 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
%q2dpzNW
7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
j3Cp o
x 7.3.4 The Surface Emission Method and Electron Damping
J);1Tpm 7.3.5 The Very-Low-Energy Electron Diffraction Method
Vu^J'>X 7.3.6 The Fermi Surface Method
j=PQoEtU'< 7.3.7 Intensities and Their Use in Band-Structure Determinations
_o' jy^ 7.3.8 Summary
#wx0xQ~,J 7.4 Experimental Band Structures
1#aOgvf 7.4.1 One- and Two-Dimensional Systems
b0riiF 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
@l$cZie 7..4.3UPS Band Structures and XPS Density of States
fnL!@WF 7.5 A Comment
K&D
-1u References
W-7yi`5 N#Qby4w > 8.Surface States, Surface Effects
\>23_d0 8.1 Theoretical Considerations
x>&1;g2r 8.2 Experimental Results on Surface States
i*9eU*i|H 8.3 Quantum-Well States
0Q]x[;!k 8.4 Surface Core-Level Shifts
wV W+~DJ References
8
6?D PKwHq<vAsB 9.Inverse Photoelectron Spectroscopy
frc>0\ 9.1 Surface States
JQQD~J1)E 9.2 Bulk Band Structures
:pDw gd 9.3 Adsorbed Molecules
GB^Ch YOb References
wgkh}b
!@ai=p 10. Spin-Polarized Photoelectron Spectroscopy
|Wi$@sWO 10.1 General Description
0-l
@U{ 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
\hv*`ukF 10.3 Magnetic Dichroism
9.#\GI ; References
%mtW-drv> fVb&=%e 11. Photoelectron Diffraction
)I.[@#- 11.1 Examples
A}H)ojG'v 11.2 Substrate Photoelectron Diffraction
py
P5^Qv 11.3 Adsorbate Photoelectron Diffraction
\8{C$"F 11.4 Fermi Surface Scans
c 6E@+xU References
g2 :^Z== -[0)n{AVvU Appendix
ldI;DoE#U1 A.1 Table of Binding Energies
!Lk|eGd* A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
'S@h._q A.3 Compilation of Work Functions
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'qbCSM References
l'B`f) Index