光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
Ox7v*[x' .I$Q3%s 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
(Gr8JpV `9E:V= 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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wi^zXcVj ?$i`K| Cj"+` C)l 目录
((&_m9a 1. Introduction and Basic Principles
l5_RG,O0A 1.1 Historical Development
,r~pf(nz 1.2 The Electron Mean Free Path
GjN/8>/ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
*yKw@@d+p 1.4 Experimental Aspects
&
9}L +/, 1.5 Very High Resolution
4scY8(1 1.6 The Theory of Photoemission
G8dC5+h 1.6.1 Core-Level Photoemission
rOQ@(aUAZ 1.6.2 Valence-State Photoemission
>Eg/ir0 1.6.3 Three-Step and One-Step Considerations
*@/1]W 1.7 Deviations from the Simple Theory of Photoemission
H&\[iZ|-N References
mRU-M| c<- F_+[ 2. Core Levels and Final States
q}P< Ejq} 2.1 Core-Level Binding Energies in Atoms and Molecules
BwMi@r
= 2.1.1 The Equivalent-Core Approximation
{`?C5<r 2.1.2 Chemical Shifts
{U@&hE
- 2.2 Core-Level Binding Energies in Solids
{JTO
Q 8& 2.2.1 The Born-Haber Cycle in Insulators
Z-X(.Q 2.2.2 Theory of Binding Energies
v zgR3r 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
~R^~?Y%+< 2.3 Core Polarization
*W,tq(%tQ 2.4 Final-State Multiplets in Rare-Earth Valence Bands
jo-jPYH T 2.5 Vibrational Side Bands
1bjhEOW 2.6 Core Levels of Adsorbed Molecules
?#~3%$> 2.7 Quantitative Chemical Analysis from Core-Level Intensities
aVkgE> References
~Sy/q]4ys* ~,[-pZ< 3. Charge-Excitation Final States: Satellites
hM$K?t 3.1 Copper Dihalides; 3d Transition Metal Compounds
iR}3 [ 3.1.1 Characterization of a Satellite
y"zgpqJ 3.1.2 Analysis of Charge-Transfer Satellites
zURxXo/\V 3.1.3 Non-local Screening
Xq:jp+WSG 3.2 The 6-eV Satellite in Nickel
#-vuY#gs 3.2.1 Resonance Photoemission
v"wxHro 3.2.2 Satellites in Other Metals
6[3oOO:uo 3.3 The Gunnarsson-Sch6nhammer Theory
lh^-L+G:Ok 3.4 Photoemission Signals and Narrow Bands in Metals
jZwv!-: References
p1~u5BE7O Mbbgsy3W 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
%]NaHf 4.1 Theory
FvpaU\D 4.1.1 General
%c+`8 wj 4.1.2 Core-Line Shape
7>
~70 4.1.3 Intrinsic Plasmons
UQ]WBS\ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
$Ro]]NUz| 4.1.5 The Total Photoelectron Spectrum
MI8f(ZJK5 4.2 Experimental Results
+9mE1$C 4.2.1 The Core Line Without Plasmons
=AEl:SY+ 4.2.2 Core-Level Spectra Including Plasmoas
>f)/z$
qn 4.2.3 Valence-Band Spectra of the Simple Metals
{Yq"%n'0 4.2.4 Simple Metals: A General Comment
Cka&b 4.3 The Background Correction
lO^Ly27 References
'Mp8!9=& :
L}Fm2^ 5. Valence Orbitals in Simple Molecules and Insulating Solids
}E[u" @} 5.1 UPS Spectra of Monatomic Gases
U~9Y9qzy, 5.2 Photoelectron Spectra of Diatomic Molecules
%C8p!)Hu 5.3 Binding Energy of the H2 Molecule
\3nu &8d 5.4 Hydrides Isoelectronic with Noble Gases
Tfasry9'8 Neon (Ne)
>4I,9TO Hydrogen Fluoride (HF)
4#<r}j12z Water (H2O)
i/Zv@GF Ammonia (NH3)
Vyy;mEBg Methane (CH4)
YY{0WWua 5.5 Spectra of the Alkali HMides
x<&2`= 5.6 Transition Metal Dihalides
VN3"$@-POK 5.7 Hydrocarbons
kH;DAphk 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
t2bv
nh 5.7.2 Linear Polymers
_FpZc?= 5.8 Insulating Solids with Valence d Electrons
x?10^~R 5.8.1 The NiO Problem
]0[Gc
\h} 5.8.2 Mort Insulation
0}LBnV 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
2pr#qh8 5.8.4Band Structures of Transition Metal Compounds
u.\FNa 5.9 High—Temperature Superconductors
LWH(bs9U 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
"gt-bo., 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
WG~|sLg 5.9.3 The Superconducting Gap
ub/Z'! 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
#6g9@tE 5.9.5 Core—Level Shifts
g+(Cs 5.10 The Fermi Liquid and the Luttinger Liquid
x}^:Bs+j 5.11 Adsorbed Molecules
?=u/&3Cw 5.11.1 Outline
Go^a~Sf$ 5.11.2 CO on Metal Surfaces
j 3/ I= References
1gK<dg gu1:%raXd 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
N@qP}/}8 6.1 Theory of Photoemission:A Summary of the Three-Step Model
^|^yw gK 6.2 Discussion of the Photocurrent
c:*[HO\ 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
T[?wbYfW 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
2wCSjAWWh( 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
2SjH7
' 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
?"hrCEHV{9 6.3.1 Band Structure Regime
;+-@AYl 6.3.2 XPS Regime
`EBI$;! 6.3.3 Surface Emission
R #f*QXv 6.3.4 One-Step Calculations
F.rNh`44 6.4 Thermal Effects
Xmmb^2I 6.5 Dipole Selection Rules for Direct Optical Transitions
H[WsHq;T+9 References
<w,NMu" VtTTvP3 7.Band Structtire and Angular-Resolved Photoelectron Spectra
ul@swp 7.1 Free-Electron Final—State Model
{th=MldJ? 7.2 Methods Employing Calculated Band Structures
3p+V~n.+ 7.3 Methods for the Absolute Determination of the Crystal Momentum
%#_"Ie 7.3.1 Triangulation or Energy Coincidence Method
DPWt=IFU 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
"V=IG{. 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
5SB!)F] 7.3.4 The Surface Emission Method and Electron Damping
,H)v+lI 7.3.5 The Very-Low-Energy Electron Diffraction Method
Ri 7.3.6 The Fermi Surface Method
xmM!SY> 7.3.7 Intensities and Their Use in Band-Structure Determinations
9mmkFaBQ 7.3.8 Summary
m}-*B1 7.4 Experimental Band Structures
9 HiH6f^5 7.4.1 One- and Two-Dimensional Systems
/VmtQ{KTt+ 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
VYR<x QA 7..4.3UPS Band Structures and XPS Density of States
21T#NYfew 7.5 A Comment
2@Nt6r References
VxP cC+ K]{x0A 8.Surface States, Surface Effects
+GYO<N7 8.1 Theoretical Considerations
IgmCZ?l&0 8.2 Experimental Results on Surface States
LJ8 t@ui 8.3 Quantum-Well States
>eC>sTPQ{ 8.4 Surface Core-Level Shifts
_Xqa_6+/ References
G (3wI} "y9]>9:$- 9.Inverse Photoelectron Spectroscopy
Vsj1!}X: 9.1 Surface States
ZLGglT'EW> 9.2 Bulk Band Structures
1PN!1= F} 9.3 Adsorbed Molecules
q\$k'(k>35 References
QomihQnc u\AL`'v 10. Spin-Polarized Photoelectron Spectroscopy
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