光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
z k}AGw 45wtl/^9 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
"@hd\w{. XKws_ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
JN9>nC!Zy_ RjvW*'2G ^<-r57pz y9d"sqyh 市场价:¥88.00
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B K=w'1U .1;UEb|T 2IM31 . 目录
=+wd"Bu 1. Introduction and Basic Principles
d,l?{Ln 1.1 Historical Development
WG6
0 1.2 The Electron Mean Free Path
gELG/6l 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
KgkRs?'z 1.4 Experimental Aspects
{]}94T~/k 1.5 Very High Resolution
ZfqN4 1.6 The Theory of Photoemission
[yk-<}#B 1.6.1 Core-Level Photoemission
I_z(ft. 1.6.2 Valence-State Photoemission
3BCD0
%8 1.6.3 Three-Step and One-Step Considerations
pk.\IKlG] 1.7 Deviations from the Simple Theory of Photoemission
, p~1fB-/ References
RQo
a mrnPZf i 2. Core Levels and Final States
s^eiym P 2.1 Core-Level Binding Energies in Atoms and Molecules
/QyKXg6)l 2.1.1 The Equivalent-Core Approximation
`q<W %'Tb$ 2.1.2 Chemical Shifts
aif;h!
?y 2.2 Core-Level Binding Energies in Solids
qT(6T P 2.2.1 The Born-Haber Cycle in Insulators
h,m 90Hd+ 2.2.2 Theory of Binding Energies
r*l3Hrho~K 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
^O+ (eA7E 2.3 Core Polarization
P* `*^r3 2.4 Final-State Multiplets in Rare-Earth Valence Bands
v
'+]T= 2.5 Vibrational Side Bands
;H~<.QW 2.6 Core Levels of Adsorbed Molecules
=8?Kn@nMN 2.7 Quantitative Chemical Analysis from Core-Level Intensities
lh"*$.j- References
)'U0n`= ]1<GZ` 3. Charge-Excitation Final States: Satellites
\/Mx|7< 3.1 Copper Dihalides; 3d Transition Metal Compounds
aU_Hl+; 3.1.1 Characterization of a Satellite
u7[}pf$} 3.1.2 Analysis of Charge-Transfer Satellites
mvZ#FF1,J 3.1.3 Non-local Screening
8;DDCop 8L 3.2 The 6-eV Satellite in Nickel
\$wkr 3.2.1 Resonance Photoemission
`nl n@ ; 3.2.2 Satellites in Other Metals
[rT.k5_ 3.3 The Gunnarsson-Sch6nhammer Theory
^HJ?k:u 3.4 Photoemission Signals and Narrow Bands in Metals
=zyA~}M2 References
|M?vFF]TN ;cI*"-I:F 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
Df^F)\7!N? 4.1 Theory
qy3@>
1G 4.1.1 General
pqfX}x 4.1.2 Core-Line Shape
Ck
Nl;g l 4.1.3 Intrinsic Plasmons
yk`qF'4] 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
]oB~8d 4.1.5 The Total Photoelectron Spectrum
)?$[iu7 s 4.2 Experimental Results
r!2U#rz 4.2.1 The Core Line Without Plasmons
z~ C8JY: 4.2.2 Core-Level Spectra Including Plasmoas
\c:$eF 4.2.3 Valence-Band Spectra of the Simple Metals
e(?w h 4.2.4 Simple Metals: A General Comment
@m#OhERv 4.3 The Background Correction
+
t5SrO!` References
pZ.b
X LTTMa-]Yy 5. Valence Orbitals in Simple Molecules and Insulating Solids
hWT
jN 5.1 UPS Spectra of Monatomic Gases
E&P2E3P 5.2 Photoelectron Spectra of Diatomic Molecules
v4n< G- 5.3 Binding Energy of the H2 Molecule
"r-P[EKpL 5.4 Hydrides Isoelectronic with Noble Gases
#0P_\X`E Neon (Ne)
3T2]V? Hydrogen Fluoride (HF)
}xk(aM_ Water (H2O)
__g
k:a>oQ Ammonia (NH3)
}uZs)UQ|$ Methane (CH4)
RSp wU;o6z 5.5 Spectra of the Alkali HMides
"B_3<RSL 5.6 Transition Metal Dihalides
V 95o(c.p 5.7 Hydrocarbons
eThaH0 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
%y6(+I#P 5.7.2 Linear Polymers
;miif 5.8 Insulating Solids with Valence d Electrons
K($l>PB,y@ 5.8.1 The NiO Problem
\wK&wRn) 5.8.2 Mort Insulation
t*gZcw5 r 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
4o*i(W 5.8.4Band Structures of Transition Metal Compounds
f4"UI-8;n 5.9 High—Temperature Superconductors
.:$(o& 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
Ktq 4b%{ 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
??,[-Oi 5.9.3 The Superconducting Gap
X7},|cmD_ 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
DiFYVR<@ 5.9.5 Core—Level Shifts
V*giF`gq 5.10 The Fermi Liquid and the Luttinger Liquid
0[MYQl` 5.11 Adsorbed Molecules
"b} mVrFh 5.11.1 Outline
fMUcVTFe 5.11.2 CO on Metal Surfaces
.AfZ5s]/F References
&lQ%;)' D'g,<-ahl 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
?=? _32O 6.1 Theory of Photoemission:A Summary of the Three-Step Model
k]~o=MLmj 6.2 Discussion of the Photocurrent
qjB:6Jq4q 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
5=pE*ETJ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
xyp{_ MZ 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
sQJ\{'g 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
!dLu($P 6.3.1 Band Structure Regime
n
i#jAwkN5 6.3.2 XPS Regime
F]\
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1q6)R/P 6.3.4 One-Step Calculations
S,m( 6.4 Thermal Effects
@^{`!>Vt 6.5 Dipole Selection Rules for Direct Optical Transitions
~g{j)"1 References
;c!> = bA^uzE 7.Band Structtire and Angular-Resolved Photoelectron Spectra
a:BW*Hy{\ 7.1 Free-Electron Final—State Model
|P
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A)f-r 7.3 Methods for the Absolute Determination of the Crystal Momentum
d:%b 7.3.1 Triangulation or Energy Coincidence Method
2n<Mu Q] 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
yw^Pok5. 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
$n\P w 7.3.4 The Surface Emission Method and Electron Damping
J(7#yg%5 7.3.5 The Very-Low-Energy Electron Diffraction Method
`i.BB jx` 7.3.6 The Fermi Surface Method
[wGj?M} 7.3.7 Intensities and Their Use in Band-Structure Determinations
J @Hg7Faz 7.3.8 Summary
7he73 7.4 Experimental Band Structures
+:S`] 7.4.1 One- and Two-Dimensional Systems
Cv**iW 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
$ev+0m_ 7..4.3UPS Band Structures and XPS Density of States
O^L]2BVC 7.5 A Comment
4ud(5m;Rle References
/2tA
n 2W,9HSu8 8.Surface States, Surface Effects
`3;EJDEdbi 8.1 Theoretical Considerations
)UzJ2Pa<+_ 8.2 Experimental Results on Surface States
ZQ`8RF *v 8.3 Quantum-Well States
s<I)THC 8.4 Surface Core-Level Shifts
X +`Dg:: References
+_5*4>MC K*~{M+lU7 9.Inverse Photoelectron Spectroscopy
;ku>_sG- 9.1 Surface States
\<7Bx[/D4 9.2 Bulk Band Structures
-S sgW 9.3 Adsorbed Molecules
Lq(=0U\"P References
?P
kJG,~ H*=cw< 10. Spin-Polarized Photoelectron Spectroscopy
)U&9d 10.1 General Description
%e
iV^> 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
C QkY6 10.3 Magnetic Dichroism
y``\^F References
UqK.b}s `<7\Zl 11. Photoelectron Diffraction
..N6]u 11.1 Examples
Y{}
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(TZK~+]@sb 11.3 Adsorbate Photoelectron Diffraction
cMT7Bd 11.4 Fermi Surface Scans
7`|'Om?' References
x@NfN*?/+i S?688 Appendix
K[T0);hZR A.1 Table of Binding Energies
%' DOFiU A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
,=)DykP A.3 Compilation of Work Functions
?8~l+m6s$ References
4|x_C-@ Index